Abstract
Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene-carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and - at the same time - donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Methane / analogs & derivatives*
-
Methane / chemistry
-
Models, Molecular
-
Molecular Structure
-
Organogold Compounds / chemistry*
-
Organophosphorus Compounds / chemistry*
-
Phosphines / chemistry*
Substances
-
Organogold Compounds
-
Organophosphorus Compounds
-
Phosphines
-
carbene
-
Methane