doiSerbia

Calculation of complex chemical equilibrium compositions of composite rocket propellants combustion products

Filipović Miloš (Military Technical Institute, Belgrade)
Kilibarda Nikola (Military Technical Institute, Belgrade)

An adequate method for calculating chemical equilibrium in a predominantly gaseous, multi-component reactive mixture was investigated and successfully applied. This method involves the stated equilibrium reaction scheme, including, first, the formation of chemical species, of which concentrations prevail in the mixture, then the formation of gaseous atomic species by dissociation of previous ones, and, finally, the formation of complex chemical species from the atomic species. A computer program, which permits calculations of equilibrium compositions by the iteration procedure, has been developed. The results of calculations have been compared with data obtained by the programs OPHELIE, MICROPEP, and the program SPP, as documented in the NASA-Lewis Code, which is presently the world-wide standard. All comparisons gave satisfactory agreement.

Keywords: composite propellants, combustion, combustion products, chemical equilibrium