Journal of the Serbian Chemical Society 2024 Volume 89, Issue 2, Pages: 215-230
https://doi.org/10.2298/JSC231023103A
Full text (
2739 KB)
Physicochemical properties of bioplastic based on hydroxyethylcellulose and polyvinylpyrrolidone blend
Anwar Budiman 
(Material Chemistry Research Group, Chemistry Programs, Faculty of Mathematics and Natural Sciences Education, Universitas Pendidikan Indonesia, Bandung, Indonesia), [email protected]
Nurhashiva Citra (Material Chemistry Research Group, Chemistry Programs, Faculty of Mathematics and Natural Sciences Education, Universitas Pendidikan Indonesia, Bandung, Indonesia)
Arwa Raihanah Wafa (Material Chemistry Research Group, Chemistry Programs, Faculty of Mathematics and Natural Sciences Education, Universitas Pendidikan Indonesia, Bandung, Indonesia)
Yuliani Galuh (Material Chemistry Research Group, Chemistry Programs, Faculty of Mathematics and Natural Sciences Education, Universitas Pendidikan Indonesia, Bandung, Indonesia)
The aim of this study is to develop a bioplastic based on hydroxyethylcellulose (HEC) and polyvinilpyrrolidone (PVP) which is applied as packaging materials. The effect of incorporation of PVP into HEC on the physicochemical properties of its blend films are investigated. The FTIR and DSC analysis denote that incorporation of PVP induce the intermolecular hydrogen bonds to occur more intensely. The XRD diffractograms indicate that the incorporation of PVP reduces the crystallinity of the film. The mechanical properties of the films become greater as the PVP content increases, and the optimum composition of HEC/PVP is at 5:3 mass ratio with a tensile strength of 34.8±3.4 MPa; elongation at break 104.3±4.9 %; and an elastic modulus of 0.10±0.02 GPa. The SEM and DSC analysis signify an excellent compatibility and miscibility between HEC and PVP. The incorporation of PVP increase the transparency and hydrophilicity of the film. The water vapor transmission rate of the films is relatively unchanged due to the incorporation of PVP. The TGA and DSC analysis reveal that the incorporation of PVP increases the thermal stability and the glass transition temperature of the film. This bioplastic film could be an alternative for biodegradable packaging material.
Keywords: polyblend, biodegradable plastic, cellulose derivative, biopolymers, HEC/PVP blend
Show references
S. Jeremic, J. Milovanovic, M. Mojicevic, S. S. Bogojevic, J. Nikodinovic-Runic, J. Serb. Chem. Soc. 85 (2020) 1507 (https://doi.org/10.2298/JSC200720051J)
K. E. Rivadeneira-Velasco, C. A. Utreras-Silva, A. Díaz-Barrios, A. E. Sommer-Márquez, J. P. Tafur, R. M. Michell, Polymers 13 (2021) 3227 (https://doi.org/10.3390/polym13193227)
G. El-Fawal, H. Hong, X. Song, J. Wu, M. Sun, C. He, X. Mo, Y. Jiang, H. Wang, Food Packag. Shelf Life 23 (2020) 100462 (https://doi.org/10.1016/j.fpsl.2020.100462)
G. El-Fawal, J. Food Sci. Technol. 51 (2014) 2234 (https://doi.org/10.1007/s13197-013- 1255-9)
A. Nesic, J. Ruzic, M. Gordic, S. Ostojic, D. Micic, A. Onjia, Composites, B 110 (2017) 56 (http://dx.doi.org/10.1016/j.compositesb.2016.11.016)
N. Tabassum, M. A. Khan, Sci. Hortic. 259 (2020) 108853 (https://doi.org/10.1016/j.scienta.2019.108853)
H. Somashekarappa, Y. Prakash, K. Hemalatha, T. Demappa, R. Somashekar, Indian J. Mater. Sci. 2013 (2013) 307514 (http://dx.doi.org/10.1155/2013/307514)
X. Zhang, H. Guo, W. Luo, G. Chen, N. Xiao, G. Xiao, C. Liu, Front. Bioeng. Biotechnol. 10 (2022) 01 (https://doi.org/10.3389/fbioe.2022.989893)
E. Di Giuseppe, in Reference Module in Earth Systems and Environmental Sciences, S. A. Elias, Еd., Elsevier, Amsterdam, 2018 (https://doi.org/10.1016/B978-0-12-409548-9.10909-1)
Z. Lu, J. Huang, S. E, J. Li, L. Si, C. Yao, F. Jia, M. Zhang, Carbohydr. Polym. 250 (2020) 116919 (https://doi.org/10.1016/j.carbpol.2020.116919)
N. Aqdas, M. Z. Khalid, T. Shazia, A. Waseem, S. Muhammad, Z. Mohammad, Int. J. Biol. Macromol. 15 (2020) 993 (https://doi.org/10.1016/j.ijbiomac.2019.10.254)
M. El Achaby, Y. Essamlali, N. El Miri, A. Snik, K. Abdelouahdi, A. Fihri, A. Solhy, J. Appl. Polym. Sci. 131 (2014) 41042 (https://doi.org/10.1002/app.41042)
X. Sui, Y. Chu, J. Zhang, H. Zhang, H. Wang, T. Liu, C. Han, Adv. Polym. Technol. 2020 (2020) 8859658 (https://doi.org/10.1155/2020/8859658)
C. S. Reddy, P. K. Babu, K. Sudhakar, M. N. Prabhakar, P. Sudhakar, S. V. Pratap, S. H. R. Prasad, V. N. E. Reddy, M. C. S. Subha, K. C. Rao, Polym. Res. J. 7 (2013) 253 (https://www.researchgate.net/profile/Palla-Kumara-Babu/publication/281743945_miscibility_studies_of_hydroxyethyl_cellulose_and_poly_e thylene_glycol_polymer_blends/links/55f7c01a08aeafc8ac0569a1/miscibility-studies-ofhydroxyethyl- cellulose-and-poly-ethylene-glycol-polymer-blends.pdf)
G. El Fawal, H. Hong, X. Song, J. Wu, M. Sun, L. Zhang, C. He, X. Mo, H. Wang, Appl. Biochem. Biotechnol. 191 (2020) 1624 (https://doi.org/10.1007/s12010-020-03282-1)
K. C. Rao, M. C. S. Subha, C. S. Reddy, P. K. Babu, K. Sudhakar, M. N. Prabhakar, Y. Maruthi, U. S. K. Rao, Int. J. Basic Appl. Chem. Sci. 3 (2013) 73 (https://www.cibtech.org/J-CHEMICALSCIENCES/PUBLICATIONS/2013/Vol%203%20No.%201/10-004...Chowdoji...Miscibility...Blends...73-83.pdf)
B. Anwar, B. Bundjali, Y. Sunarya, I. M. Arcana, Fibers Polym. 22 (2021) 1228 (https://doi.org/10.1007/s12221-021-0765-8)
M. F. Zaltariov, Cellul. Chem. Technol. 55 (2021) 981 (https://doi.org/10.35812/CelluloseChemTechnol.2021.55.84)
Y. H. Wen, C. H. Tsou, M. R. de Guzman, D. Huang, Y. Q. Yu, C. Gao, Z. H. Wang, Polym. Bull. 79 (2022) 3847 (https://doi.org/10.1007/s00289-021-03666-1)
D. A. Rusmawati, I. Yuliasih, T. C. Sunarti, IOP Conference Series: Earth and Environmental Science, Vol. 443, (2020) International Conference on Food and Bio- Industry 2019, 29-30 July 2019, Bandung, Indonesia (https://doi.org/10.1088/1755-1315/443/1/012054)
E. Karavas, E. Georgarakis, D. Bikiaris, Int. J. Pharm. 313 (2006) 189 (https://doi.org/10.1016/j.ijpharm.2006.01.015)
Y. Prakash, D. Mahadevaiah, H. Somashekarappa, T. Demappa, R. Somashekar, J. Res. Updates Polym. Sci. 1 (2012) 24 (http://dx.doi.org/10.6000/1929-5995.2012.01.01.4)
R. Kumar, I. Mishra, G. Kumar, J. Polym. Environ. 29 (2021) 3770 (https://doi.org/10.1007/s10924-021-02143-0)
S. Patil, A. K. Bharimalla, A. Mahapatra, J. Dhakane-Lad, A. Arputharaj, M. Kumar, A. S. M. Raja, N. Kambli, Food Biosci. 44 (2021) 101352 (https://doi.org/10.1016/j.fbio.2021.101352)
A. Gleadall, in Modelling Degradation of Bioresorbable Polymeric Medical Devices, J. Pan, Ed., Elsevier Ltd., Amsterdam, 2015, p. 163 (https://doi.org/10.1533/9781782420255.2.163)
C. Ding, M. Zhang, G. Li, Carbohydr. Polym. 119 (2015) 194 (http://dx.doi.org/10.1016/j.carbpol.2014.11.057)
M. Voronova, N. Rubleva, N. Kochkina, A. Afineevskii, A. Zakharov, O. Surov, Nanomaterials 8 (2018) 1011 (https://doi.org/10.3390/nano8121011)
S. Wang, J. Ren, W. Li, R. Sun, S. Liu, Carbohydr. Polym. 103 (2014) 94 (http://dx.doi.org/10.1016/j.carbpol.2013.12.030)
J. F. Mukerabigwi, S. Lei, L. Fan, H. Wang, S. Luo, X. Ma, J. Qin, X. Huang, Y. Cao, RSC Adv. 6 (2016) 31607 (https://doi.org/10.1039/C6RA01759B)
M. Fiayaz, K. M. Zia, M. A. Javaid, S. Rehman, S. A. S. Chatha, M. Zuber, Korean J. Chem. Eng. 37 (2020) 2351 (https://doi.org/10.1007/s11814-020-0664-5)
A. D. French, M. S. Cintron, Cellulose 20 (2013) 583 (https://doi.org/10.1007/s10570-010-9420-z)
A. Emblem, in Packaging Technology: Fundamentals, Materials and Processes, A. Emblem, H. Emblem, Eds., Elsevier Ltd., Amsterdam, 2012, p. 287 (https://doi.org/10.1533/9780857095701.2.287)
S. Guzman-Puyol, J. J. Benítez, J. A. Heredia-Guerrero, Food Res. Int. 161 (2022) 111792 (https://doi.org/10.1016/j.foodres.2022.111792)
A. Aydogdu, E. Yildiz, Z. Ayhan, Y. Aydogdu, G. Sumnu, S. Sahin, Eur. Polym. J. 112 (2019) 477 (https://doi.org/10.1016/j.eurpolymj.2019.01.006)
R. Kumar, B. Rai, G. A. Kumar, J. Polym. Environ. 27 (2019) 2963 (https://doi.org/10.1007/s10924-019-01588-8)
T. Huhtamäki, X. Tian, J. T. Korhonen, R. H. Ras, Nat. Protoc. 13 (2018) 1521 (https://doi.org/10.1038/s41596-018-0003-z)
R. Poonguzhali, S. K. Basha, V. S. Kumari, Polym. Bull. 74 (2017) 2185 (https://doi.org/10.1007/s00289-016-1831-z)
P. Lu, H. Xiao, W. Zhang, G. Gong, Carbohydr. Polym. 111 (2014) 524 (https://doi.org/10.1016/j.carbpol.2014.04.071)
H. Y. Wu, T. X. Liu, C. H. Hsu, Y. S. Cho, Z. J. Xu, S. C. Liao, S. Y. Lien, Materials 10 (2017) 821 (https://doi.org/10.3390/ma10070821)
A. Zheng, Y. Xue, D. Wei, S. Li, H. Xiao, Y. Guan, Soft Mater. 12 (2014) 179 (https://doi.org/10.1080/1539445X.2013.831357)
T. T. Kararli, J. B. Hurlbut, T. E. Needham, J. Pharm. Sci. 79 (1990) 845 (https://doi.org/10.1002/jps.2600790922)
F. H. Zulkifli, F. S. J. Hussain, W. S. W. Harun, M. M. Yusoff, Int. J. Biol. Macromol. 122 (2019) 562 (https://doi.org/10.1016/j.ijbiomac.2018.10.156)
K. Beyaz, C. Vaca-Garcia, E. Vedrenne, N. Haddadine, A. Benaboura, S Thiebaud-Roux, Int. J. Polym. Anal. Charact. 24 (2019) 245 (https://doi.org/10.1080/1023666X.2019.1567085)
T. M. M. Swamy, B. Ramaraj, Siddaramaiah, J. Appl. Polym. Sci. 112 (2009) 2235 (https://doi.org/10.1002/app.29738)
J. B. Yin, K. Luo, X. S. Chen, V. V. Khutoryanskiy, Carbohydr. Polym. 63 (2006) 238 (https://doi.org/10.1016/j.carbpol.2005.08.041)
V. Mutalik, L. S. Manjeshwar, A. Wali, M. Sairam, B. Sreedhar, K. V. S. N. Raju, T. M. Aminabhavi, J. Appl. Polym. Sci. 106 (2007) 765 (https://doi.org/10.1002/app.25427).