Assessment of Residuality of Hymexazol in Strawberry (Fragaria × ananassa) Crop by a Modified QuEChERS Method and Liquid Chromatography Tandem-Mass Spectrometry
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents and Chemicals
2.2. Field Experiments
2.2.1. Crop Establishment
2.2.2. Treatments and Applications
2.2.3. Leaf and Fruit Sampling
2.3. Sample Pretreatment
2.4. Instrumental Parameters
2.5. Analytical Method Validation
3. Results and Discussion
3.1. Method Validation
3.1.1. Linearity
3.1.2. Linear Range of Work
3.1.3. Precision under Repeatability Conditions and Intermediate Precision
3.1.4. Accuracy (% R)
3.1.5. Limit of Detection (LOD) and Limit of Quantification (LOQ)
3.2. Dissipation and Residuality of Hymexazol in Leaves and Fruits of Strawberry
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Event | Days after Transplant | Activity |
---|---|---|
Transplant | 0 | - |
First application | 35 | Application in drench |
Second application | 48 | Application in drench |
49 | First leaf sampling | |
50 | Second leaf sampling | |
Third application | 62 | Application in drench |
Fourth application | 69 | Application in drench |
70 | First fruit sampling | |
71 | Second fruit sampling |
Linearity | Recovery and Intra-Laboratory Precision (%) | ||||||
---|---|---|---|---|---|---|---|
Analyte | Lineal Range of Method (mg kg−1) | Lineal Range of the System (mg/L) | Coefficient of Determination (R2) | Recovery (%) | CV (%) | LOD (mg kg−1) | LOQ (mg kg−1) |
HYM | 0.025–0.5 | 0.025–1.0231 | 0.9995 | 82.55 ± 6.8 | 8. 24 | 0.017 | 0.051 |
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Báez-Sañudo, M.A.; Jiménez-Ortega, L.A.; Bastidas-Bastidas, P.d.J. Assessment of Residuality of Hymexazol in Strawberry (Fragaria × ananassa) Crop by a Modified QuEChERS Method and Liquid Chromatography Tandem-Mass Spectrometry. Agronomy 2022, 12, 3110. https://doi.org/10.3390/agronomy12123110
Báez-Sañudo MA, Jiménez-Ortega LA, Bastidas-Bastidas PdJ. Assessment of Residuality of Hymexazol in Strawberry (Fragaria × ananassa) Crop by a Modified QuEChERS Method and Liquid Chromatography Tandem-Mass Spectrometry. Agronomy. 2022; 12(12):3110. https://doi.org/10.3390/agronomy12123110
Chicago/Turabian StyleBáez-Sañudo, Manuel Alonzo, Luis Alfonso Jiménez-Ortega, and Pedro de Jesús Bastidas-Bastidas. 2022. "Assessment of Residuality of Hymexazol in Strawberry (Fragaria × ananassa) Crop by a Modified QuEChERS Method and Liquid Chromatography Tandem-Mass Spectrometry" Agronomy 12, no. 12: 3110. https://doi.org/10.3390/agronomy12123110