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| Names | |
|---|---|
| Preferred IUPAC name
Butanedial[1] | |
| Other names
Succinaldehyde
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| Identifiers | |
3D model (JSmol)
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|
| ChemSpider | |
| ECHA InfoCard | 100.010.304 |
PubChem CID
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|
| UNII | |
CompTox Dashboard (EPA)
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|
| |
| |
| Properties | |
| C4H6O2 | |
| Molar mass | 86.09 |
| Appearance | colourless liquid |
| Density | 1.064 g/cm3 |
| Boiling point | 58 °C (136 °F; 331 K) at 9 mm Hg |
| with hydration | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Succinaldehyde or succindialdehyde is an organic compound with the formula (C2H4(CHO)2. It is a colorless viscous liquid.[2] Typical of some other saturated dialdehydes, succinaldehyde is handled as the hydrates or methanol-derived acetal. It is a precursor to tropinone.[3] Succinaldehyde can be used as a crosslinking agent for proteins, but it is less widely used than the related dialdehyde glutaraldehyde.
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Transcription
Preparation and reactions
Succinaldehyde is generated by the oxidation of tetrahydrofuran with chlorine followed by hydrolysis of the chlorinated product. It can also be prepared by the hydroformylation of acrolein or the acetals thereof. Oxidation of 2,5-dimethoxytetrahydrofuran with hydrogen peroxide is yet another route to succinaldehyde.[2]
In the presence of water, succinaldehyde converts to the cyclic hydrate.[4] In methanol it converts to the cyclic acetal, 2,5-dimethoxyltetrahydrofuran.[5]
References
- ^ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. p. 908. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
- ^ a b Bennett, Steven H.; Aggarwal, Varinder K. (2022). "Organocatalytic Dimerization of Succinaldehyde". Organic Syntheses. 99: 139–158. doi:10.15227/orgsyn.099.0139.
- ^ U.S. patent 2,710,883
- ^ Hardy, P. M.; Nicholls, A. C.; Rydon, H. N. (1972). "The Hydration and Polymerisation of Succinaldehyde, Glutaraldehyde, and Adipaldehyde". Journal of the Chemical Society, Perkin Transactions 2 (15): 2270. doi:10.1039/P29720002270.
- ^ Christian Kohlpaintner; Markus Schulte; Jürgen Falbe; Peter Lappe; Jürgen Weber (2008). "Aldehydes, Aliphatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a01_321.pub2. ISBN 978-3527306732.
This page was last edited on 28 March 2024, at 14:48