Version 1
: Received: 5 January 2024 / Approved: 12 January 2024 / Online: 12 January 2024 (06:56:18 CET)
How to cite:
Wang, W.; Liu, L.-L.; Chen, S.-Y.; Han, C.-L.; Zhu, S.-E. Surfactant-Assisted Synthesis of Ca3(BTC)2 Metal-Organic Framework for the Removal of Heavy Metal. Preprints2024, 2024010985. https://doi.org/10.20944/preprints202401.0985.v1
Wang, W.; Liu, L.-L.; Chen, S.-Y.; Han, C.-L.; Zhu, S.-E. Surfactant-Assisted Synthesis of Ca3(BTC)2 Metal-Organic Framework for the Removal of Heavy Metal. Preprints 2024, 2024010985. https://doi.org/10.20944/preprints202401.0985.v1
Wang, W.; Liu, L.-L.; Chen, S.-Y.; Han, C.-L.; Zhu, S.-E. Surfactant-Assisted Synthesis of Ca3(BTC)2 Metal-Organic Framework for the Removal of Heavy Metal. Preprints2024, 2024010985. https://doi.org/10.20944/preprints202401.0985.v1
APA Style
Wang, W., Liu, L. L., Chen, S. Y., Han, C. L., & Zhu, S. E. (2024). Surfactant-Assisted Synthesis of Ca<sub>3</sub>(BTC)<sub>2 </sub>Metal-Organic Framework for the Removal of Heavy Metal. Preprints. https://doi.org/10.20944/preprints202401.0985.v1
Chicago/Turabian Style
Wang, W., Cheng-Liang Han and San-E Zhu. 2024 "Surfactant-Assisted Synthesis of Ca<sub>3</sub>(BTC)<sub>2 </sub>Metal-Organic Framework for the Removal of Heavy Metal" Preprints. https://doi.org/10.20944/preprints202401.0985.v1
Abstract
Novel Ca3(BTC)2 metal-organic frameworks with different sizes and shapes constructed by Ca2+ and trimesic acid as metal center and ligands respectively were synthesized by a surfactant-assisted method. The relationship between the quantity of surfactant and the particle morphology of the product have been further studied. The samples were characterized by scanning electron microscope, powder X-ray diffraction and Inductively coupled plasma mass spectrometry. The results indicated that the size and shape of Ca3(BTC)2 could be regulated by changing the quantity of surfactant. Rod- and sheet-like Ca3(BTC)2 MOFs have been readily availabled. The removal kinetics of heavy metals of Pb(II) were also studied by rod-like Ca3(BTC)2. The results showed that as-synthesized Ca3(BTC)2 could effectively remove heavy metals of Pb(II) from the sewage.
Keywords
Metal-organic frameworks; Surfactant; ion-exchange; heavy metal; removal
Subject
Chemistry and Materials Science, Materials Science and Technology
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.