Petrangeli Papini, M.; Cerra, S.; Feriaud, D.; Pettiti, I.; Lorini, L.; Fratoddi, I. Biochar/Biopolymer Composites for In-Situ Groundwater Remediation. Preprints2024, 2024061407. https://doi.org/10.20944/preprints202406.1407.v1
APA Style
Petrangeli Papini, M., Cerra, S., Feriaud, D., Pettiti, I., Lorini, L., & Fratoddi, I. (2024). Biochar/Biopolymer Composites for In-Situ Groundwater Remediation. Preprints. https://doi.org/10.20944/preprints202406.1407.v1
Chicago/Turabian Style
Petrangeli Papini, M., Laura Lorini and Ilaria Fratoddi. 2024 "Biochar/Biopolymer Composites for In-Situ Groundwater Remediation" Preprints. https://doi.org/10.20944/preprints202406.1407.v1
Abstract
(max 200 words): The contamination of groundwater is a serious concern for ecosystems and human health. In this regard, biochar represents a promising low-cost and sustainable material for in-situ groundwater remediation. Herein, biochar waste of biomass energy production process derived from pine wood gasification at 950°C was used as active carbonaceous material in combination with different biopolymers: chitosan (CS), alginate (ALG), potato starch (PST), and carboxymethylcellulose (CMC) to produce BC@biopolymer composite materials. Different concentrations of biochar (0.3–1.0 g·L-1) and biopolymers (0.2–20.0 g·L-1) were tested and blending mode was used as simple and straightforward strategy to obtain BC composites. Scanning electron microscopy (FE-SEM), UV-Visible, infrared (FT-IR) spectroscopy, specific surface area (BET method), pore volume, and pore size distribution (textural parameters), dynamic light scattering (DLS), and ζ-potential were used to investigate the composite chemical structure, stability, and to assess the interaction among counterparts. On optimized formulations, breakthrough tests and batch adsorption isotherms on trichloroethylene (TCE) as a model contaminant were performed to evaluate the capability of composites to be delivered through a porous medium determining the transport properties, (hydrodynamic dispersion retention percentage, and adsorption capacity). This biopolymer-modified biochar holds significant promise as a sustainable and effective solution to address various groundwater pollution challenges.
Copyright:
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