Impact of Corrosion in Simulated Body Fluid on Fatigue Characteristics of 3D-Printed Polylactic Acid-Coated AM60 Magnesium Alloys
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Manufacturing Method
2.2. Corrosion Test
2.3. Fatigue Test
2.4. Fracture Surface Analysis
3. Results and Discussion
4. Conclusions
- Due to corrosion, the weight of the sample decreased by 35%.
- The corrosion rate decreased in the first seven days and then increased.
- Compared to the PF-AM60 sample, the PF-AM60-PLA specimen on average had a 49% increase in fatigue lifetime.
- Despite using a 10-times stronger solution, the fatigue lifetime of CF-AM60-PLA specimens is reduced by only 35% compared to CF-AM60 samples.
- The separation of coating from glue and glue from Mg was observed in the specimens.
- Cleavage plates caused by brittle fractures and striations during fatigue load were seen on the failure surface.
- Corrosion products, including microcracks and holes, were seen on the fracture surfaces of CF samples, which caused stress concentration and crack growth.
- Holes caused by the release of gases were observed in the PLA coating layers, which were fabricated by 3D printing.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Mg | Mn | Zn | Si | Al | Ni | Cu |
---|---|---|---|---|---|---|
Bulk | 0.3 | 0.07 | 0.04 | 5.5 | 0.004 | 0.01 |
Parameters | Speed (mm/s) | Nozzle Temperature (°C) | Bed Temperature (°C) | Infill in the First and Last Layer (%) | Infill in the Inner Layer (%) | Layer Height (µm) | Nozzle Diameter (mm) |
---|---|---|---|---|---|---|---|
Value | 50 | 245 | 60 | 100 | 50 | 50 | 0.4 |
Ions | Concentration (mM) | Ions | Concentration (mM) |
---|---|---|---|
Mg2+ | 15.0 | HPO42− | 10.0 |
K+ | 50.0 | HCO3− | 42.0 |
Na+ | 1420.0 | Cl− | 1478.0 |
Ca2+ | 25.0 | SO42− | 5.0 |
Test Conditions | All Data | Average Data | ||||
---|---|---|---|---|---|---|
(MPa) | b | R2 | b | R2 | ||
PF-AM60 | 506.92 | −0.137 | 0.9407 | 589.97 | −0.151 | 0.9534 |
CF-AM60 | 419.50 | −0.133 | 0.9144 | 494.11 | −0.148 | 0.9999 |
PF-AM60-PLA | 1444.60 | −0.208 | 0.9849 | 1502.30 | −0.211 | 0.9999 |
CF-AM60-PLA | 429.96 | −0.146 | 0.6109 | 618.86 | −0.180 | 0.6785 |
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Ashraf Talesh, S.A.; Azadi, M. Impact of Corrosion in Simulated Body Fluid on Fatigue Characteristics of 3D-Printed Polylactic Acid-Coated AM60 Magnesium Alloys. Surfaces 2024, 7, 88-107. https://doi.org/10.3390/surfaces7010007
Ashraf Talesh SA, Azadi M. Impact of Corrosion in Simulated Body Fluid on Fatigue Characteristics of 3D-Printed Polylactic Acid-Coated AM60 Magnesium Alloys. Surfaces. 2024; 7(1):88-107. https://doi.org/10.3390/surfaces7010007
Chicago/Turabian StyleAshraf Talesh, Seyed Ali, and Mohammad Azadi. 2024. "Impact of Corrosion in Simulated Body Fluid on Fatigue Characteristics of 3D-Printed Polylactic Acid-Coated AM60 Magnesium Alloys" Surfaces 7, no. 1: 88-107. https://doi.org/10.3390/surfaces7010007