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Keywords = Jablonsky diagram

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10 pages, 1699 KiB  
Review
Electronically Excited States of Free Radicals
by Igor V. Khudyakov
Physchem 2023, 3(3), 332-341; https://doi.org/10.3390/physchem3030023 - 7 Aug 2023
Viewed by 1652
Abstract
Formation of the excited doublet (D) and quartet (Q) states of free radicals under their photoexcitation is discussed. The relative positions of the D and Q states are compared to the positions of the photoexcited states of organic molecules (Jablonsky diagram). A number [...] Read more.
Formation of the excited doublet (D) and quartet (Q) states of free radicals under their photoexcitation is discussed. The relative positions of the D and Q states are compared to the positions of the photoexcited states of organic molecules (Jablonsky diagram). A number of representative cases of the excited states of free radicals detected by their transient absorption or emission are presented. A special case of the population having the lowest Q state in some radicals is discussed. A spin–statistical factor in the reactions of Q and D is debated. Full article
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