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25 pages, 1724 KiB  
Article
Revealing the Nexus between Fertilizer Composition and the Performance of Common Bean (Phaseolus vulgaris L.) Genotypes in the Himalayan Heartland of India
by Amani Lakshmi Vemulakonda, Ahmad Abdullah Saad, Shamal Shasang Kumar, Owais Ali Wani, Lal Singh, Subhash Babu, Inayat Mustafa Khan, Fahim Jeelani Wani, Shaheen Kauser Jan, Khalid M. Elhindi and Mohamed A. Mattar
Sustainability 2024, 16(14), 6234; https://doi.org/10.3390/su16146234 (registering DOI) - 21 Jul 2024
Abstract
Gaining insight into the interplay between crucial fertilizers and their impact on crop characteristics is crucial for enhancing the agricultural output and promoting sustainable crop administration. The objective of this study was to assess the growth, productivity, and nutrient-use efficiency (NUE) of common [...] Read more.
Gaining insight into the interplay between crucial fertilizers and their impact on crop characteristics is crucial for enhancing the agricultural output and promoting sustainable crop administration. The objective of this study was to assess the growth, productivity, and nutrient-use efficiency (NUE) of common bean genotypes with varying levels of NPK. In the RCBD field study, three genotypes of common bean were cultivated—SKUA-WB-5000/1446 (V1), SKUA-WB-5002/185 (V2), and SKUA-WB-5003/1492 (V3)—together with six combinations of NPK (N2:P2O5:K2O kg ha−1). The findings indicated that the height of the plants had a positive correlation with elevated NPK levels subsequent to the maximum point in NPK 10-20-10. The V1 genotype exhibited superior growth and productive traits, particularly with regard to its higher seed index and much greater quantity of pods plant−1. This indicates that the V1 genotype may be a suitable choice for cultivating common beans and highlights the importance of adjusting nutrient levels to ensure sustainable crop management. This study suggests applying 30-60-30 NPK kg ha−1 of fertilizer for genotypes V1 and V3, while genotype V2 should receive 40-80-40 NPK kg ha−1 under rainfed circumstances. Full article
(This article belongs to the Section Sustainable Agriculture)
17 pages, 2135 KiB  
Article
Cover Crop Effects on Surface Runoff and Subsurface Flow in Rainfed Hillslope Farming and Connections to Water Quality
by Víctor Hugo Durán Zuazo, Belén Cárceles Rodríguez, Simón Cuadros Tavira, Baltasar Gálvez Ruiz and Iván Francisco García-Tejero
Land 2024, 13(7), 1103; https://doi.org/10.3390/land13071103 (registering DOI) - 21 Jul 2024
Abstract
Abstract: Surface runoff and subsurface flow patterns were monitored in hillside runoff plots in almond and olive orchards with soils covered with spontaneous plants over two hydrological years. The experimental runoff plots were located on the south flank of the Sierra Nevada (Lanjarón, [...] Read more.
Abstract: Surface runoff and subsurface flow patterns were monitored in hillside runoff plots in almond and olive orchards with soils covered with spontaneous plants over two hydrological years. The experimental runoff plots were located on the south flank of the Sierra Nevada (Lanjarón, SE Spain) at 580 m a.s.l. with an area of 40 m2 (10 m × 4 m). The surface and subsurface discharge were collected and measured at different soil depths (0, 5, 10, 25, and 50 cm), and the dissolved nutrient concentrations (NO3–N, NH4–N, PO4–P, and K) were determined. According to the findings, the subsurface flow pathways drained most of the rainfall water compared with surface runoff, which was affected by plant cover. The influence of rainfall intensity (I30) on surface runoff was more meaningful than that on subsurface flow. Throughout the monitoring period, the runoff coefficients at soil depths of 0, 5, 10, 25, and 50 cm averaged 0.04, 0.11, 0.14, 0.17, and 0.18, respectively. Subsurface flow was one of the dominant pathways for N and K loss, whereas P loss mainly occurred via surface runoff. Moreover, the concentrations in subsurface flow were higher than the recommended level for standard water quality for NO3–N, NH4–N, and PO4–P. Subsurface flow was the main route of dissolved nutrient delivery, making these nutrients available to the root systems of trees, where nutrient uptake is more likely to occur. Thus, by lessening surface runoff and encouraging surface vegetation coverage to facilitate the recycling of nutrients and buffer the rainfall’s impact on the soil surface, nutrient loss control can be achieved. Full article
13 pages, 308 KiB  
Article
Emergence of blaNDM-5 and blaOXA-232 Positive Colistin- and Carbapenem-Resistant Klebsiella pneumoniae in a Bulgarian Hospital
by Rumyana Markovska, Petya Stankova, Georgi Popivanov, Ivanka Gergova, Kalina Mihova, Ventsislav Mutafchiyski and Lyudmila Boyanova
Antibiotics 2024, 13(7), 677; https://doi.org/10.3390/antibiotics13070677 (registering DOI) - 21 Jul 2024
Abstract
The rapid spread of carbapenemase-producing strains has led to increased levels of resistance among Gram-negative bacteria, especially enterobacteria. The current study aimed to collect and genetically characterize the colistin- and carbapenem-resistant isolates, obtained in one of the biggest hospitals (Military Medical Academy) in [...] Read more.
The rapid spread of carbapenemase-producing strains has led to increased levels of resistance among Gram-negative bacteria, especially enterobacteria. The current study aimed to collect and genetically characterize the colistin- and carbapenem-resistant isolates, obtained in one of the biggest hospitals (Military Medical Academy) in Sofia, Bulgaria. Clonal relatedness was detected by RAPD and MLST. Carbapenemases, ESBLs, and mgrB were investigated by PCR amplification and sequencing, replicon typing, and 16S rRNA methyltransferases with PCRs. Fourteen colistin- and carbapenem-resistant K. pneumoniae isolates were detected over five months. Six carbapenem-resistant and colistin-susceptible isolates were also included. The current work revealed a complete change in the spectrum of carbapenemases in Bulgaria. blaNDM-5 was the only NDM variant, and it was always combined with blaOXA-232. The coexistence of blaOXA-232 and blaNDM-5 was observed in 10/14 (72%) of colistin- and carbapenem-resistant K. pneumoniae isolates and three colistin-susceptible isolates. All blaNDM-5- and blaOXA-232-positive isolates belonged to the ST6260 (ST101-like) MLST type. They showed great mgrB variability and had a higher mortality rate. In addition, we observed blaOXA-232 ST14 isolates and KPC-2-producing ST101, ST16, and ST258 isolates. The colistin- and carbapenem-resistant isolates were susceptible only to cefiderocol for blaNDM-5- and blaOXA-232-positive isolates and to cefiderocol and ceftazidime/avibactam for blaOXA-232- or blaKPC-2-positive isolates. All blaOXA-232-positive isolates carried rmtB methylase and the colE replicon type. The extremely limited choice of appropriate treatment for patients infected with such isolates and their faster distribution highlight the need for urgent measures to control this situation. Full article
(This article belongs to the Section Mechanism and Evolution of Antibiotic Resistance)
23 pages, 8318 KiB  
Article
Analysis of the Effect of Sampling Probe Geometry on Measurement Accuracy in Supersonic Gas Flow
by Wanlin Zhang, Yingtao Chen, Yanting Ai, Pengpeng Sha and Xinlong Yang
Aerospace 2024, 11(7), 595; https://doi.org/10.3390/aerospace11070595 (registering DOI) - 21 Jul 2024
Abstract
The accuracy of sampling of gas components has a significant impact on the measurement of various performance parameters in the combustion chamber of an aero-engine. In order to investigate the effect of the probe geometry of a six-point gas sampling probe on sampling [...] Read more.
The accuracy of sampling of gas components has a significant impact on the measurement of various performance parameters in the combustion chamber of an aero-engine. In order to investigate the effect of the probe geometry of a six-point gas sampling probe on sampling accuracy in supersonic gas flow, a three-dimensional probe gas flow characteristic solution model is established through numerical simulation methods of components of transport and fluid–solid coupling. Probes with three angles of 28°, 30°, and 32° and an optimized conical probe are constructed. The sampling accuracy of the probes with different geometries is compared and evaluated by the deviation of the component volume fraction before and after sampling and the resulting combustion efficiency error. This paper presents a set of calculation methods for solving the relative deviation of volume fraction by an iterative method based on the ideal gas law and the Redlich–Kwong equation (R-K equation). The method is designed to solve the exact component volume fraction problem in the simulation calculation. The study results demonstrate that the 28° and optimized conical probes improve sampling accuracy more effectively than the original 30° structure. The deviation of the volume fractions of the two structures is less than 1.7%, and the combustion efficiency error is less than 0.09%. The developed iterative calculation method can significantly reduce the theoretical calculation error to less than 0.06%. The experimental data of the test bench are in good agreement with the simulation results, thereby demonstrating the reliability and accuracy of the sampling probe following structural optimization. Full article
(This article belongs to the Section Aeronautics)
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23 pages, 29155 KiB  
Article
Analysis of Thermoelastic Contact of Gas-Lubricated Rough Sealing Faces
by Shaoxian Bai, Yangyang Chen and Jing Yang
Materials 2024, 17(14), 3600; https://doi.org/10.3390/ma17143600 (registering DOI) - 21 Jul 2024
Abstract
Friction and wear are the main failure sources of face seals. When the surfaces of sealing rings exhibit greater roughness, the level of friction might increase and lead to sealing failure. Therefore, in this paper, based on the elastic contact hypothesis of rough [...] Read more.
Friction and wear are the main failure sources of face seals. When the surfaces of sealing rings exhibit greater roughness, the level of friction might increase and lead to sealing failure. Therefore, in this paper, based on the elastic contact hypothesis of rough and wavy surfaces and the influence of temperature on the elastic modulus of materials, a thermoelastic contact lubrication model of a gas-lubricated end seal is established. The novelty and advantage of this study is that it takes the effect of surface roughness into consideration during thermoelastic analysis of gas-lubricated seals. The film pressure, temperature, contact force and deformation of a gas spiral groove-faced seal are numerically determined. The influence of surface roughness on the contact distribution, deformation and temperature of the end-face seal at different speeds and pressures is analyzed. The film thickness increases as the rotational speed increases from 1 rpm to 2000 rpm, while the contact pressure sharply decreases from 0.25 kPa to 0. The analysis shows that the roughness contact mainly happens on the inner side of the rings due to convergent distortion of the seal faces, which easily causes partial wear of the seal faces. Moreover, it can also be found that the spiral grooves on the sealing surface can produce obvious hydrodynamic pressure effect due to the function of shear speed when the speed increases to 2000 rpm, while the film temperature increases from 293.3 K to about 306 K. The greater surface roughness results in a larger temperature rise under low-rotational-speed and lower-seal-pressure conditions, which further increases the risk of severe wear or even failure of the seal faces. Full article
18 pages, 1845 KiB  
Article
Learning a Context-Aware Environmental Residual Correlation Filter via Deep Convolution Features for Visual Object Tracking
by Sachin Sakthi Kuppusami Sakthivel, Sathishkumar Moorthy, Sathiyamoorthi Arthanari, Jae Hoon Jeong and Young Hoon Joo
Mathematics 2024, 12(14), 2279; https://doi.org/10.3390/math12142279 (registering DOI) - 21 Jul 2024
Abstract
Visual tracking has become widespread in swarm robots for intelligent video surveillance, navigation, and autonomous vehicles due to the development of machine learning algorithms. Discriminative correlation filter (DCF)-based trackers have gained increasing attention owing to their efficiency. This study proposes “context-aware environmental residual [...] Read more.
Visual tracking has become widespread in swarm robots for intelligent video surveillance, navigation, and autonomous vehicles due to the development of machine learning algorithms. Discriminative correlation filter (DCF)-based trackers have gained increasing attention owing to their efficiency. This study proposes “context-aware environmental residual correlation filter tracking via deep convolution features (CAERDCF)” to enhance the performance of the tracker under ambiguous environmental changes. The objective is to address the challenges posed by intensive environment variations that confound DCF-based trackers, resulting in undesirable tracking drift. We present a selective spatial regularizer in the DCF to suppress boundary effects and use the target’s context information to improve tracking performance. Specifically, a regularization term comprehends the environmental residual among video sequences, enhancing the filter’s discrimination and robustness in unpredictable tracking conditions. Additionally, we propose an efficient method for acquiring environmental data using the current observation without additional computation. A multi-feature integration method is also introduced to enhance the target’s presence by combining multiple metrics. We demonstrate the efficiency and feasibility of our proposed CAERDCF approach by comparing it with existing methods using the OTB2015, TempleColor128, UAV123, LASOT, and GOT10K benchmark datasets. Specifically, our method increased the precision score by 12.9% in OTB2015 and 16.1% in TempleColor128 compared to BACF. Full article
(This article belongs to the Special Issue Advanced Computational Intelligence)
12 pages, 2196 KiB  
Article
Vasorelaxant and Hypotensive Effects of Galla chinensis in Rats
by Sujin Shin, Junkyu Park, Ho-Young Choi, Youngmin Bu and Kyungjin Lee
Int. J. Mol. Sci. 2024, 25(14), 7962; https://doi.org/10.3390/ijms25147962 (registering DOI) - 21 Jul 2024
Abstract
Previous studies have revealed the medicinal and therapeutic effects of Galla chinensis. However, no studies have focused on the antihypertensive effects of G. chinensis. Therefore, we aimed to determine the vasorelaxant and hypotensive effects of G. chinensis 50% ethanolic extract (GCE). [...] Read more.
Previous studies have revealed the medicinal and therapeutic effects of Galla chinensis. However, no studies have focused on the antihypertensive effects of G. chinensis. Therefore, we aimed to determine the vasorelaxant and hypotensive effects of G. chinensis 50% ethanolic extract (GCE). To evaluate the vascular relaxing effect of GCE, experiments were conducted using aortic segments dissected from Sprague Dawley rats. GCE showed a vasorelaxant effect via the nitric oxide/cyclic guanosine 3′,5′-monophosphate pathway, inhibiting Ca2+ channels, and activating K+ channels. The hypotensive effects of GCE were evaluated in spontaneously hypertensive rats (SHRs). The SHRs were randomly divided into a control group and orally administered GCE group (100 or 300 mg/kg). The systolic and diastolic blood pressure decreased significantly by −19.47 ± 4.58% and −31.14 ± 7.66% in the GCE 100 mg/kg group, and −21.64 ± 2.40% and −31.91 ± 5.75% in the GCE 300 mg/kg group at 4 h after administration. Considering its vasorelaxant and hypotensive effects, our results indicate that GCE may be a valuable solution for the control of hypertension. However, further studies on the long-term administration and toxicity of GCE are required. Full article
(This article belongs to the Special Issue Health Promoting Benefits of Natural Products and Functional Foods)
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24 pages, 9818 KiB  
Article
Recombinant Human TSH Fails to Induce the Proliferation and Migration of Papillary Thyroid Carcinoma Cell Lines
by Georgios Kalampounias, Athina Varemmenou, Christos Aronis, Irene Mamali, Athanasios-Nasir Shaukat, Dionysios V. Chartoumpekis, Panagiotis Katsoris and Marina Michalaki
Cancers 2024, 16(14), 2604; https://doi.org/10.3390/cancers16142604 (registering DOI) - 21 Jul 2024
Abstract
Thyrotropin (TSH) suppression is required in the management of patients with papillary thyroid carcinoma (PTC) to improve their outcomes, inevitably causing iatrogenic thyrotoxicosis. Nevertheless, the evidence supporting this practice remains limited and weak, and in vitro studies examining the mitogenic effects of TSH [...] Read more.
Thyrotropin (TSH) suppression is required in the management of patients with papillary thyroid carcinoma (PTC) to improve their outcomes, inevitably causing iatrogenic thyrotoxicosis. Nevertheless, the evidence supporting this practice remains limited and weak, and in vitro studies examining the mitogenic effects of TSH in cancerous cells used supraphysiological doses of bovine TSH, which produced conflicting results. Our study explores, for the first time, the impact of human recombinant thyrotropin (rh-TSH) on human PTC cell lines (K1 and TPC-1) that were transformed to overexpress the thyrotropin receptor (TSHR). The cells were treated with escalating doses of rh-TSH under various conditions, such as the presence or absence of insulin. The expression levels of TSHR and thyroglobulin (Tg) were determined, and subsequently, the proliferation and migration of both transformed and non-transformed cells were assessed. Under the conditions employed, rh-TSH was not adequate to induce either the proliferation or the migration rate of the cells, while Tg expression was increased. Our experiments indicate that clinically relevant concentrations of rh-TSH cannot induce proliferation and migration in PTC cell lines, even after the overexpression of TSHR. Further research is warranted to dissect the underlying molecular mechanisms, and these results could translate into better management of treatment for PTC patients. Full article
(This article belongs to the Section Molecular Cancer Biology)
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15 pages, 6012 KiB  
Article
Numerical and Experimental Modal Analysis of a Gyroid Inconel 718 Structure for Stiffness Specification in the Design of Load-Bearing Components
by Katarina Monkova, Sanjin Braut, Peter Pavol Monka, Ante Skoblar and Martin Pollák
Materials 2024, 17(14), 3595; https://doi.org/10.3390/ma17143595 (registering DOI) - 21 Jul 2024
Abstract
The study aims to investigate the modal properties of a 60 × 70 × 80 mm gyroid structure made of Inconel 718 with 67.5% porosity. The geometry model for sample production was created using the software PTC Creo, whereas the geometry model for [...] Read more.
The study aims to investigate the modal properties of a 60 × 70 × 80 mm gyroid structure made of Inconel 718 with 67.5% porosity. The geometry model for sample production was created using the software PTC Creo, whereas the geometry model for numerical analysis was created using the Python application ScaffoldStructures. FE analysis was performed using ANSYS 2024 R1 software. Free boundary conditions were used in experimental modal analysis to ensure feasibility. The analysis identified the first four natural frequencies ranging from 10 to 16 kHz. The results revealed that the first natural frequency corresponds to the first torsional frequency about the Z axis, the second to the first flexural mode in the XZ plane, the third to the first bending mode in the YZ plane, and the fourth to the first torsional mode about the X axis. Small differences between the results of numerical and experimental modal analysis can be attributed to geometric errors in the manufactured sample, careless removal from the platform, and due to reduction in the complexity of the numerical FE model. Employing modal analysis of a component, the stiffness of a lightweight component can be revealed. In the case of the sample with the cellular structure of gyroid type, relatively high stiffness regarding the material savings was identified, which can be advantageously used in many applications. Full article
(This article belongs to the Special Issue Preparation and Application of Regularly Structured Porous Materials)
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10 pages, 13225 KiB  
Article
Experimental Study on Microalloyed Steel with Layers Subjected to Diesel
by Noé López Perrusquia, Tomas de la Mora Ramírez, Gerardo Julián Pérez Mendoza, Víctor Hugo Olmos Domínguez, David Sánchez Huitron and Marco Antonio Doñu Ruiz
Coatings 2024, 14(7), 912; https://doi.org/10.3390/coatings14070912 (registering DOI) - 21 Jul 2024
Abstract
This work studies the mechanical behavior of microalloyed steels (API X60 and API X70) with boride layers using a boriding process and immersion in diesel. First, the microalloyed steels were borided using dehydrated boron paste at a temperature of 1273 K for 6 [...] Read more.
This work studies the mechanical behavior of microalloyed steels (API X60 and API X70) with boride layers using a boriding process and immersion in diesel. First, the microalloyed steels were borided using dehydrated boron paste at a temperature of 1273 K for 6 h, and then the borided microalloyed steels were immersed in diesel for one year. The characterization of the layers on the specimens subjected to diesel used scanning electron microscopy (SEM), energy dispersive spectroscopy, and X-ray diffraction (XRD). The evaluation of the mechanical properties was performed with tensile tests according to ASTM E8, and then the fracture surface was observed by SEM. This work contributes to the understanding of the changes in the mechanical properties of borided microalloyed steel immersed in diesel for possible potential applications in the storage of fuels, oils, hydrogen, and biofuels. Full article
(This article belongs to the Special Issue Surface Engineering, Coatings and Tribology)
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13 pages, 3717 KiB  
Article
Numerical Modeling of Hybrid Solar/Thermal Conversion Efficiency Enhanced by Metamaterial Light Scattering for Ultrathin PbS QDs-STPV Cell
by Oussama Baitiche, Fathi Bendelela, Ali Cheknane, Abdelaziz Rabehi and Elisabetta Comini
Crystals 2024, 14(7), 668; https://doi.org/10.3390/cryst14070668 (registering DOI) - 21 Jul 2024
Abstract
Ultrathin cells are gaining popularity due to their lower weight, reduced cost, and enhanced flexibility. However, compared to bulk cells, light absorption in ultrathin cells is generally much lower. This study presents a numerical simulation of a metamaterial light management structure made of [...] Read more.
Ultrathin cells are gaining popularity due to their lower weight, reduced cost, and enhanced flexibility. However, compared to bulk cells, light absorption in ultrathin cells is generally much lower. This study presents a numerical simulation of a metamaterial light management structure made of ultrathin lead sulfide colloidal quantum dots (PbS CQDs) sandwiched between a top ITO grating and a tungsten backing to develop an efficient hybrid solar/thermophotovoltaic cell (HSTPVC). The optical properties were computed using both the finite integration technique (FIT) and the finite element method (FEM). The absorptance enhancement was attributed to the excitations of magnetic polaritons (MP), surface plasmon polaritons (SPP), and lossy mode resonance (LMR). The HSTPVC with the metamaterial optical light management structure was assessed for short-circuit current density, open-circuit voltage, and conversion efficiency. The results show a conversion efficiency of 18.02% under AM 1.5 solar illumination and a maximum thermophotovoltaic conversion efficiency of 12.96% at TB = 1600 K. The HSTPVC can operate in a hybrid solar/thermal conversion state when the ITO grating is included by combining the advantages of QDs and metamaterials. This work highlights the potential for developing a new generation of hybrid STPV cells through theoretical modeling and numerical simulations. Full article
(This article belongs to the Section Hybrid and Composite Crystalline Materials)
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15 pages, 5192 KiB  
Article
Hydrochemical and Formation Mechanism Studies of Groundwater in Quaternary Aquifer in a Northern Plain of China: An Example of Beijing Plain
by Sarah Fatim Camara, Jinjun Zhou and Yongxiang Zhang
Water 2024, 16(14), 2060; https://doi.org/10.3390/w16142060 (registering DOI) - 21 Jul 2024
Abstract
Beijing Plain is a very active part of Beijing city regarding the socio-economic and human activities of the region. Over the past four decades, Beijing’s economic development and the continuous drought for nearly 10 years in the 2000s have negatively impacted the groundwater [...] Read more.
Beijing Plain is a very active part of Beijing city regarding the socio-economic and human activities of the region. Over the past four decades, Beijing’s economic development and the continuous drought for nearly 10 years in the 2000s have negatively impacted the groundwater quantity and quality. Therefore, it is necessary to investigate the present situation of groundwater chemistry in this region to develop a comprehensive database and orientation for future research on groundwater quality evaluation. Mathematical statistics, Piper’s trilinear diagram, Gibbs plots, the ion ratio method and PHREEQC software 3.7.3 were used to analyze the groundwater hydrogeochemical characteristics and formation mechanisms of the quaternary aquifers of the Beijing Plain area. Hydrogeochemical results indicated that the groundwater is slightly alkaline, with pH values ranging from 6.76 to 8.65 and an average value of 7.92. The order of major cations in groundwater was Ca2+ > Na+ > Mg2+ > K+ with average values of 66.54 mg/L, 50.58 mg/L, 23.78 mg/L, and 1.81 mg/L, respectively, while the order of major anions was HCO3 > SO42− > Cl with average values of 284.89 mg/L, 52.1 mg/L and 35.5 mg/L, respectively. The groundwater chemical types are Mg-Ca-Cl-HCO3, Na-Ca-HCO3, Mg-Ca-HCO3 and Mg-Na-HCO3. Research on the main influencing factors and PHREEQC hydrogeochemical inverse simulations results along the four pathways selected confirmed that rock weathering with sulfate, silicate and carbonate rock mineral dissolution and Na+, Mg2+ and Ca2+ ion reaction exchange influenced groundwater hydrogeochemical characteristics of the quaternary aquifers of the Beijing Plain area. Understanding the formation mechanisms of hydrogeochemistry in quaternary plains provides guidance for future studies and, through suggestions and case studies, facilitates decision-making by policy-makers on the sustainable management of groundwater resources. Full article
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17 pages, 9303 KiB  
Article
Continuous Wave Mode Test of Conduction-Cooled Nb3Sn Radio Frequency Superconducting Cavities at Peking University
by Manqian Ren, Lin Lin, Jiankui Hao, Gai Wang, Ziyu Wang, Deyang Wang, Haoyu Shen, Shengwen Quan, Fang Wang, Liwen Feng, Fei Jiao, Feng Zhu, Kun Zhu, Xueqing Yan and Senlin Huang
Appl. Sci. 2024, 14(14), 6350; https://doi.org/10.3390/app14146350 (registering DOI) - 21 Jul 2024
Abstract
A liquid helium-free cryostat for radio frequency (RF) test of the superconducting cavity is designed and constructed. Gifford-Mcmahon (G-M) cryocoolers are used to provide cooling capacity, and the heat leakage at 4 K is less than 0.02 W. Vertical and horizontal tests of [...] Read more.
A liquid helium-free cryostat for radio frequency (RF) test of the superconducting cavity is designed and constructed. Gifford-Mcmahon (G-M) cryocoolers are used to provide cooling capacity, and the heat leakage at 4 K is less than 0.02 W. Vertical and horizontal tests of two Nb3Sn cavities are carried out in the cryostat with different surface treatments outside the cavities. Both of the cavities achieve stable continuous wave (CW) operation. A novel treatment, which cold-sprayed a 3.5 mm thick Cu layer onto the outside of the cavity, enables the maintenance of an average temperature of 5.5 K in the cavity at a RF loss of 10 W, implying that the thermal stability and uniformity of the cavity has been significantly improved. Through the synergistic control of four metal film resistors, a cooling rate of 0.06 K/min near 18 K is realized, and the cavity temperature gradient is reduced to 0.17 K/m, which effectively improves the RF performance of the cavity. The maximum Eacc of the cavity reaches 3.42 MV/m, and the Q0 is 1.1 × 109. An electromagnetic–thermal coupling simulation model for the superconducting cavity is established and is in good agreement with the experimental results. The simulation results show that the cavity with a Cu-spraying treatment and the thermal links of 5N Al can satisfy the Eacc of 10 MV/m under conduction cooling. Full article
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18 pages, 2433 KiB  
Article
Tuning Mechanical Properties, Swelling, and Enzymatic Degradation of Chitosan Cryogels Using Diglycidyl Ethers of Glycols with Different Chain Length as Cross-Linkers
by Yuliya Privar, Anna Skatova, Mariya Maiorova, Alexey Golikov, Andrey Boroda and Svetlana Bratskaya
Gels 2024, 10(7), 483; https://doi.org/10.3390/gels10070483 (registering DOI) - 21 Jul 2024
Abstract
Cross-linking chitosan at room and subzero temperature using a series of diglycidyl ethers of glycols (DEs)—ethylene glycol (EGDE), 1,4-butanediol (BDDE), and poly(ethylene glycol) (PEGDE) has been investigated to demonstrate that DEs can be a more powerful alternative to glutaraldehyde (GA) for fabrication of [...] Read more.
Cross-linking chitosan at room and subzero temperature using a series of diglycidyl ethers of glycols (DEs)—ethylene glycol (EGDE), 1,4-butanediol (BDDE), and poly(ethylene glycol) (PEGDE) has been investigated to demonstrate that DEs can be a more powerful alternative to glutaraldehyde (GA) for fabrication of biocompatible chitosan cryogels with tunable properties. Gelation of chitosan with DEs was significantly slower than with GA, allowing formation of cryogels with larger pores and higher permeability, more suitable for flow-through applications and cell culturing. Increased hydration of the cross-links with increased DE chain length weakened intermolecular hydrogen bonding in chitosan and improved cryogel elasticity. At high cross-linking ratios (DE:chitosan 1:4), the toughness and compressive strength of the cryogels decreased in the order EGDE > BDDE > PEGDE. By varying the DE chain length and concentration, permeable chitosan cryogels with elasticity moduli from 10.4 ± 0.8 to 41 ± 3 kPa, toughness from 2.68 ± 0.5 to 8.3 ± 0.1 kJ/m3, and compressive strength at 75% strain from 11 ± 2 to 33 ± 4 kPa were fabricated. Susceptibility of cryogels to enzymatic hydrolysis was identified as the parameter most sensitive to cross-linking conditions. Weight loss of cryogels increased with increased DE chain length, and degradation rate of PEGDE-cross-linked chitosan decreased 612-fold, when the cross-linker concentration increased 20-fold. Full article
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15 pages, 4465 KiB  
Article
Comparison of the Temperature, Radiation, and Heat Flux Distribution of a Hydrogen and a Methane Flame in a Crucible Furnace Using Numerical Simulation
by Alexander Mages and Alexander Sauer
Hydrogen 2024, 5(3), 459-473; https://doi.org/10.3390/hydrogen5030026 (registering DOI) - 21 Jul 2024
Abstract
Sustainable technologies to replace current fossil solutions are essential to meet future CO2 emission reduction targets. Therefore, this paper compares key performance indicators of a hydrogen- and a methane-flame-fired crucible furnace with computational fluid dynamics simulations at identical firing powers, aiming to [...] Read more.
Sustainable technologies to replace current fossil solutions are essential to meet future CO2 emission reduction targets. Therefore, this paper compares key performance indicators of a hydrogen- and a methane-flame-fired crucible furnace with computational fluid dynamics simulations at identical firing powers, aiming to fully decarbonize the process. Validated numerical models from the literature were used to compare temperatures, radiation fields, radiation parameters and heat transfer characteristics. As a result, we observed higher combustion temperatures and a 19.0% higher fuel utilization rate in the hydrogen case, indicating more efficient operating modes, which could be related to the increased radiant heat flux and temperature ranges above 1750 K. Furthermore, higher scattering of the heat flux distribution on the crucible surface could be determined indicating more uneven melt bath temperatures. Further research could focus on quantifying the total fuel consumption required for the heating up of the furnace, for which a transient numerical model could be developed. Full article
(This article belongs to the Topic Hydrogen Energy Technologies, 2nd Volume)
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