Search Results (14,991)

Increased dust emissions from dryland areas and their effects on human health, ecosystem viability, and environmental change are a global concern in the face of the growing climate crisis. Dust plume emissions from the West African landmass, Sahara, and Sahel areas comprise a major fraction of the global aerosol budget. Dust plume intensity is closely related to regional winds (e.g., Harmattan, Sahara Air Layer), the Intertropical Convergence Zone, monsoonal seasonality, marine currents, and physiography. To study terrigenous material emitted from the continent over the last ~260 kyr (late Quaternary), we used X-ray fluorescence spectroscopy (XRF) to analyze a ~755 cm long marine sediment core from the eastern equatorial Atlantic Ocean, resulting in nearly 1400 discrete measurements. Spectral analysis results suggest that concentrations of elements (Rb, Sr, Si, Al) preserved in the sediments are correlated to different types of orbital climate forcing. Chemical weathering intensity indicated by the Rb/Sr ratio was sensitive to seasonal insolation variations controlled by precession cycles (23–18 kyr), which presumably reflects the relationship between monsoonal rainfall and sensible heating of the continent. Spectral analysis of silicate mineral grain size (Si/Al) showed significant 40 kyr cycles that were paced by obliquity. Based on these data, we infer that winter tradewind activity accelerated in response to the intertropical insolation gradient induced by high obliquity. High Rb/Sr ratios during the last glacial maximum and penultimate glacial maximum may have been due to a predominance of mechanical weathering over chemical weathering under dry/cool climates or the dissolution of Sr-bearing carbonates by corrosive glacial bottom waters. Full article

Preferential oxidation of carbon monoxide (CO-PROX) in H₂-rich mixture is an effective way of hydrogen purification for fuel cells. High-performance PtCo/ZSM-5 catalysts with reduced Pt loading for this process were prepared using polynuclear platinum acetate complex known as platinum acetate blue (PAB) of the empirical formula Pt(CH₃COO)_2.5 as a novel precursor. The impregnation of HZSM-5 (Si/Al = 15 and 28) with PAB and its decomposition at 200 °C resulted in the stabilization of highly dispersed Pt⁰ and PtO_x species on the zeolite surface. The catalytic properties were improved by the addition of Co(CH₃COO)₂ followed by calcination at 450 °C. Produced materials were studied by SEM, TEM, EDX, XPS, and DRIFTS methods and tested in a CO-PROX reaction. The relationship between the synthesis conditions, structure, and catalytic behavior of composites is discussed in this paper. The synergistic effect of Pt and Co was observed when they both were located together in zeolite channels. The Pt-Co interaction provides new active catalytic sites and prevents platinum aggregation during the process. Due to this, the 100% CO conversion in the wide temperature range from 50 to 130 °C is achieved for PtCo/ZSM-5 catalysts (Si/Al = 15), which is the best result compared to low-loaded Pt catalysts prepared with traditional precursors. Full article

Controlling carbon emissions is a global goal, and China is actively implementing carbon reduction measures. As a major agricultural nation, China has considerable potential for developing agricultural residues as renewable and environmentally friendly biomass energy. In this study, we obtained data on crop yields, crop-to-grain ratios, and livestock excretion coefficients to calculate the biomass resources of agricultural and livestock residues in Chinese provinces from 2013 to 2022. Crop residue biomass resources showed a distribution pattern with higher levels in the north than in the south and the east than in the west. Henan and Heilongjiang provinces consistently had the highest resource levels, exceeding 35 million tons annually for 10 years. The biomass resources from livestock residues were relatively abundant in Sichuan, Henan, Yunnan, Shandong, Hunan, and Inner Mongolia. Inner Mongolia, Sichuan, Shandong, and Henan had the greatest potential for CO₂ emission reductions, primarily located in regions abundant in biomass resources and with high traditional energy consumption levels. ArcGIS was used to apply natural break classification to categorize the potential for emission reductions from agricultural and livestock residues across China from 2013 to 2022 into five classes. Based on factors such as crop planting area and livestock numbers, the spatiotemporal distribution of factors influencing the quantity of biomass resources was examined using Geographically and Temporally Weighted Regression. A tailored and integrated approach should be used for biomass, and the development of biomass energy should be promoted through policy support and technological innovation. Full article

In the pursuit of fabricating functional ceramic nanostructures, the design of preceramic functional polymers has garnered significant interest. With their easily adaptable chemical composition, molecular structure, and processing versatility, these polymers hold immense potential in this field. Our study succeeded in focusing on synthesizing ferrocene-containing block copolymers (BCPs) based on polyacrylonitrile (PAN). The synthesis is accomplished via different poly(acrylonitrile-block-methacrylate)s via atom transfer radical polymerization (ATRP) and activators regenerated by electron transfer ATRP (ARGET ATRP) for the PAN macroinitiators. The molecular weights of the BCPs range from 44 to 82 kDa with dispersities between 1.19 and 1.5 as determined by SEC measurements. The volume fraction of the PMMA block ranges from 0.16 to 0.75 as determined by NMR. The post-modification of the BCPs using 3-ferrocenyl propylamine has led to the creation of redox-responsive preceramic polymers. The thermal stabilization of the polymer film has resulted in stabilized morphologies based on the oxidative PAN chemistry. The final pyrolysis of the sacrificial block segment and conversion of the metallopolymer has led to the formation of a porous carbon network with an iron oxide functionalized surface, investigated by scanning electron microscopy (SEM), energy dispersive X-ray mapping (EDX), and powder X-ray diffraction (PXRD). These findings could have significant implications in various applications, demonstrating the practical value of our research in convenient ceramic material design. Full article

At present, cobalt belongs to what are called critical raw materials due to its scarcity and its economic importance. Cobalt is a crucial element in the development of new technologies and applications for decarbonization, with around 40% of cobalt consumption being used for rechargeable battery materials. Additionally, cobalt-based catalysts are used in the production of hydrogen fuel cells, and this element is also employed in the production of superalloys for aerospace and power generation industries. For this reason, it is imperative to increase cobalt recycling by recovering from secondary sources, such as decommissioned lithium-ion batteries. Among the technologies for cobalt recovery, adsorption is a reliable alternative as it allows its recovery even at low concentrations in aqueous solutions and is relatively low in cost. Among the potential adsorbents for cobalt recovery, this paper reviews two of the most promising adsorbents for cobalt recovery from aqueous solutions: zeolitic and carbonaceous materials. Regarding zeolitic materials, the maximum adsorption capacities are reached by FAU-type zeolites. In the case of carbonaceous materials, the actual trend is to obtain activated carbons from a wide range of carbon sources, including waste, the adsorption capacities, on average, being larger than the ones reached with zeolitic materials. Additionally, activated carbons allow, in many cases, the selective separation of cobalt from other ions which are present at the same time in the aqueous solutions such as lithium. Full article

Litter’s chemical complexity influences carbon (C) cycling during its decomposition. However, the chemical and microbial mechanisms underlying the divergence or convergence of chemical complexity under UV radiation remain poorly understood. Here, we conducted a 397-day field experiment using ¹³C cross-polarization magic-angle spinning nuclear magnetic resonance (¹³C-CPMAS NMR) to investigate the interactions among the initial chemistry, microbial communities, and UV radiation during decomposition. Our study found that the initial concentrations of O-substituted aromatic C, di-O-alkyl C, and O-alkyl C in Deschampsia caespitosa were higher than those in Kobresia tibetica. Litter’s chemical composition exhibited divergent patterns based on the initial chemistry, UV radiation, and decay time. Specifically, D. caespitosa consistently displayed higher concentrations of di-O-alkyl C and O-alkyl C compared to K. tibetica, regardless of the UV exposure and decay time. Additionally, litter’s chemical complexity was positively correlated with changes in the extracellular enzyme activities, particularly those involved in lignin, cellulose, and hemicellulose degradation, which accounted for 9%, 20%, and 4% of the variation in litter’s chemical complexity, respectively. These findings highlighted the role of distinct microbial communities in decomposing different C components through catabolism, leading to chemical divergence in litter. During the early decomposition stages, oligotrophic Planctomycetes and Acidobacteria metabolized O-alkyl C and di-O-alkyl C under UV-blocking conditions. In contrast, copiotrophic Actinobacteria and Chytridiomycota utilized these components under UV radiation exposure, reflecting their ability to thrive under UV stress conditions due to their rapid growth strategies in environments rich in labile C. Our study revealed that the inherent differences in the initial O-alkyl C and di-O-alkyl C contributed to the chemical divergence, while UV radiation further influenced this divergence by shifting the microbial community composition from oligotrophic to copiotrophic species. Thus, differences in the initial litter chemistry, microbial community, and UV radiation affected the quantity and quality of plant-derived C during decomposition. Full article

The automotive industry is experiencing radical changes under the pressure of institutions that are increasingly reducing the limits on CO₂ and pollutant emissions from road vehicles powered by internal combustion engines (ICEs). A way to decarbonize the transport sector without disrupting current automotive production is the adoption of alternative fuels for internal combustion engines (ICEs). Hydrogen is very attractive, thanks to the zero-carbon content and very high laminar flame speed, allowing for extending the lean burn limit. Other alternative fuels are methanol and ethanol. This work deals with the conversion of a small-sized passenger car powered by a three-cylinder spark ignition (SI) engine for the use of alternative fuels. In particular, the spark timing has been optimized to improve the fuel economy under every operating condition. The optimization procedure is based on the MATLAB/Simulink^® R2024a-GT-Power co-simulation analysis and minimizes the fuel consumption by varying the spark timing independently for each cylinder. In particular, at full load, the algorithm reduces the spark timing only for the cylinder in which knock is detected, reducing fuel consumption by about 2% compared to the base calibration. This approach will be adopted in future activities to understand how the use of alternative fuels affects the ignition control strategy. Full article

Carbon storage (C-storage) is a critical indicator of ecosystem services, and it plays a vital role in maintaining ecological balance and driving sustainability. Its assessment provides essential insights for enhancing environmental protection, optimizing land use, and formulating policies that support long-term ecological and economic sustainability. Previous research on C-storage in the Yellow River Basin has mainly concentrated on the spatiotemporal fluctuations of C-storage and the investigation of natural influencing factors. However, research combining human activity factors to explore the influences on C-storage is limited. In this paper, based on the assessment of the spatiotemporal evolution of C-storage in the region along the Middle and Lower Yellow River (MLYR), the influences of anthropogenic and natural factors on C-storage were explored from the perspective of sustainable development. The findings reflected the relationship between socio-economic activities and the ecological environment from a sustainable development perspective, providing important scientific evidence for the formulation of sustainability policies in the region. We noticed the proportion of arable land was the highest, reaching 40%. The increase of construction land because of the fast urbanization mainly came from arable land and grassland. During the past 15 years, the cumulative loss of C-storage was 71.17 × 10⁶ t. The high-value of C-storage was primarily situated in hilly areas, and the area of C-storage hotspots was shrinking. The aggregation effect of low-value C-storage was strengthening, while that of high-value C-storage was weakening. The dominant factors (q > 0.5) influencing the spatiotemporal variation of C-storage in the region along the Middle Yellow River (MYR) were temperature and precipitation, while the primary factor in the region along the Lower Yellow River (LYR) was temperature. Overall, meteorological factors were the main determinants across the entire study area. Additionally, compared to the MYR, anthropogenic factors had a smaller impact on the spatiotemporal evolution of C-storage in the LYR, but their influence has been increasing over time. Full article

Carcinogenesis is closely related to the expression, maintenance, and stability of DNA. These processes are regulated by one-carbon metabolism (1CM), which involves several vitamins of the complex B (folate, B2, B6, and B12), whereas alcohol disrupts the cycle due to the inhibition of folate activity. The relationship between nutrients related to 1CM (all aforementioned vitamins and alcohol) in breast cancer has been reviewed. The interplay of genes related to 1CM was also analyzed. Single nucleotide polymorphisms located in those genes were selected by considering the minor allele frequency in the Caucasian population and the linkage disequilibrium. These genes were used to perform several in silico functional analyses (considering corrected p-values < 0.05 as statistically significant) using various tools (FUMA, ShinyGO, and REVIGO) and databases such as the Kyoto Encyclopedia of Genes and Genomes (KEGG) and GeneOntology (GO). The results of this study showed that intake of 1CM-related B-complex vitamins is key to preventing breast cancer development and survival. Also, the genes involved in 1CM are overexpressed in mammary breast tissue and participate in a wide variety of biological phenomena related to cancer. Moreover, these genes are involved in alterations that give rise to several types of neoplasms, including breast cancer. Thus, this study supports the role of one-carbon metabolism B-complex vitamins and genes in breast cancer; the interaction between both should be addressed in future studies. Full article

Alkali-activated materials (AAMs) are favoured for their low carbon emissions, excellent mechanical properties, and excellent chemical resistance. In this paper, ternary alkali-activated cementitious materials were prepared from slag, steel slag, and lithium slag to investigate their strength and resistance to sulphate attack. A series of experiments were conducted using a variety of material combinations, alkali activator combinations, water–binder ratios, and exposure environments. These experiments employed both macro and micro comparative analyses. The hydration reaction products, physical phase composition, and microstructure of the ground granulated furnace slag, lithium slag, and steel slag (GLS) ternary AAMs were analysed using x-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). It was experimentally demonstrated that the GLS ternary AAMs had excellent compressive strength, good resistance to sodium sulphate erosion, and that resistance to magnesium sulphate erosion decreased with time. This study contributes to the advancement of knowledge regarding the utilisation of lithium slag and steel slag, and offers new insights into the field of alkali-activated cementitious materials and their resistance to sulphate erosion. Full article

The creation of supercapacitors with superior energy density and power capabilities is critical for advanced energy storage solutions. Ionic liquid electrolytes offer a promising alternative in this respect. However, improving their cycle stability and efficiency is a complex task requiring extensive research and significant effort. The high viscosity of ionic liquids (ILs) limits their lifetime, but this can be mitigated by increasing the temperature or adding solvents. In this research, the electrochemical performance of symmetric activated carbon supercapacitors with 1-Ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF₄) and different ratios of acetonitrile (ACN) as electrolytes were investigated. Long-term galvanostatic charge/discharge tests, impedance studies, and cyclic voltammetry were performed at temperatures between 24 to 60 °C. The addition of ACN to the ionic liquid increased electrochemical stability and reduced internal resistance, with the best performance observed at a 1:2 volume ratio of EMIMBF₄ to ACN. This supercapacitor exhibited 87% cyclic stability after 5000 charge/discharge cycles in the voltage range of 0.05–2.8 V and a current rate of 1 Ag⁻¹. It also achieved an energy density of 23 Whkg⁻¹ and a power density of 748 Wkg⁻¹. The supercapacitors were stable at elevated temperatures up to 60 °C, showing no degradation after operation under various thermal conditions. Full article

To contribute to the realization of the goal of carbon peak and carbon neutrality, the non-polluting and sustainable nature of new energy sources such as wind, photovoltaic power, and energy storage has gained widespread attention, and new-energy distributed power generation technology is being applied on a large scale. Due to the high penetration, decentralization, and source–load uncertainty in new-energy distributed power generation, the traditional centralized regulation and control method struggles to meet the demand for scheduling flexibility in a distribution network. Hence, a cluster-optimization scheduling method for distribution networks considering source–load–storage synergy is proposed in this paper. Firstly, by using the comprehensive index of cluster-active power balance and electrical-distance modularity as the objective function, a simulated annealing algorithm is proposed to improve the genetic algorithm for solving a distribution network cluster division model. Then, based on the results of the distributed cluster segmentation, an optimal scheduling model is established, with the objective of minimizing the comprehensive operating costs by considering clusters as units. Inter-cluster power interactions are then used to reduce cluster operating costs and to meet intra-cluster power balance requirements by automatically setting time-sharing tariffs between the clusters. Finally, an IEEE33 node system is taken as an example for verification. The results show that the proposed distribution network cluster division method has better electrical coupling and active power balance and that the optimal scheduling method of clusters can effectively reduce the system operation costs. Hence, the method studied in this paper can increase the flexibility of regional distribution grid scheduling and the reliability of the power supply, reduce regional energy mobility to reduce energy consumption, improve the utilization efficiency of energy, and promote the sustainable development of new energy access to the distribution network. Full article

The Sustainable Development Goals (SDGs) have set the agenda for 2030, calling for collective global efforts to deal with climate change while seeking a balance between economic development and environmental protection. Although many countries are exploring emission reduction paths, mainly from government and corporate perspectives, addressing climate change is also an individual responsibility and requires public participation in collective action. The millennial generation constitutes the current workforce and will be the leaders in climate action for the next 30 years. Therefore, our study focuses on the Chinese millennial generation, conducting in-depth semi-structured interviews with 50 participants in qualitative research to explore their low-carbon lifestyles, the barriers, and enablers in switching to a wider range of low-carbon lifestyles. There are three main results: (1) Based on our study samples, there is an indication that Chinese millennials have a positive attitude towards transitioning to a low-carbon lifestyle. Women demonstrate a stronger willingness to adopt low-carbon behaviors in their daily household activities compared to men. However, their involvement in governance in the context of transitioning to a low-carbon society is limited, with most women assuming execution roles in climate action rather than decision-making positions. (2) Millennial’s low-carbon life transition is accompanied by technological innovation and progress. However, this progress brings some new forms of resource waste, and reasonable policy-making is essential. (3) Personal economic interests and the satisfaction of their consumption needs will drive millennials to reduce carbon emissions in their daily lives, but it requires the guidance of reasonable policy-making and synergies among various stakeholders. This research will help policymakers better understand the current status and potential issues related to people’s low-carbon actions, enabling the formulation of more rational guiding policies. It can also help other stakeholders learn about millennials’ demands and take more effective collective action toward carbon reduction. Full article

Real textile wastewater (RTWW) poses significant environmental challenges. RTWW typically contains high levels of organic compounds, such as dyes, as well as inorganic substances like salts. These contaminants can harm aquatic life when released into water bodies without appropriate treatment. RTWW was subjected to a series of sequential treatments: exchange resins for removing ions, advanced oxidation with bicarbonate-activated peroxide to degrade organic matter, and a biological treatment based on the Zahn–Wellens test to remove remaining chemical oxygen demand (COD) The advanced oxidation process based on the activation of H₂O₂ with NaHCO₃ (catalyzed with cobalt impregnated on a pillared clay, Co/Al–PILC)) was optimized using central composite design (CCD) and response surface methodology (RSM). After the process integration, reductions in ion concentrations, chemical oxygen demand (COD), and total organic carbon content (TOC) were achieved. Reduced hardness (99.94%) and ions (SO₄²⁻ and acid black 194 dye of 99.88 and 99.46%, respectively), COD (96.64%), and TOC (96.89%), guaranteeing complete treatment of RTWW, were achieved. Additionally, the biodegradability index of RTWW increased from 0.28 ± 0.01 to 0.90 ± 0.01, and phytotoxicity was reduced, going from a phytotoxic that inhibited the germination of lettuce seeds to a phytostimulant after biological treatment with activated sludge. Full article

Coalbed methane is released externally due to coal mining activities. Given its low concentration, which renders utilization challenging, China annually vents approximately 285 billion cubic meters of coalbed methane into the atmosphere, leading to significant energy waste and greenhouse gas emissions. To enhance the utilization rate of coalbed methane, mitigate these emissions, and promote a “green and low-carbon” energy supply, this article investigates pressure swing adsorption technology for purifying coalbed methane and analyzes the advantages, disadvantages, and application scopes of three processes: separation based on equilibrium effects, kinetic effects, and steric hindrance effects. The research findings reveal that equilibrium effect-based adsorption is particularly advantageous for purifying low-concentration coalbed methane, effectively capturing methane (CH₄). Conversely, when dealing with medium- to high-concentration coalbed methane, methods leveraging kinetic effects prove more favorable. Within the context of equilibrium effects, activated carbon serves as a suitable adsorbent; however, achieving high-purity products entails substantial energy consumption. The methane saturation adsorption capacity of novel activated carbons has reached 2.57 mol/kg. Kinetic effect-based adsorbents, primarily carbon molecular sieves and zeolite molecular sieves, are characterized by lower energy demands. Currently, coal-based molecular sieves have achieved a CH₄/N₂ equilibrium separation factor of 4.21, and the amount of raw coal required to produce one ton of carbon molecular sieve has decreased to 2.63 tons. In light of the rapid advancement of intensive coal mining operations and the swift implementation of smart mine construction, there is an urgent need to intensify research on large-scale purification technologies for low-concentration coalbed methane. This will provide the technical foundation necessary for achieving “near-zero emission” of mine gas and facilitate the achievement of the goals of carbon peak and carbon neutrality. Full article