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19 pages, 1124 KiB  
Article
Increasing Wheat Protein and Yield through Sulfur Fertilization and Its Relationship with Nitrogen
by Gustavo A. Roa, Eber Addí Quintana-Obregón, Mariela González-Renteria and Dorivar A. Ruiz Diaz
Nitrogen 2024, 5(3), 553-571; https://doi.org/10.3390/nitrogen5030037 (registering DOI) - 26 Jun 2024
Viewed by 65
Abstract
Sulfur fertilization plays a crucial role in wheat (Triticum aestivum L.) production, influencing both protein concentration and grain yield. Wheat, being one of the most important food crops globally, requires efficient management of essential nutrients, including sulfur and nitrogen, to achieve optimal [...] Read more.
Sulfur fertilization plays a crucial role in wheat (Triticum aestivum L.) production, influencing both protein concentration and grain yield. Wheat, being one of the most important food crops globally, requires efficient management of essential nutrients, including sulfur and nitrogen, to achieve optimal production. This study aimed to quantify the effect of sulfur fertilization on wheat protein concentration and grain yield and the relationship with nitrogen through two complementary methods: a comprehensive meta-analysis and a controlled greenhouse experiment. The meta-analysis, encompassing 55 studies from 20 countries with 545 comparisons, quantified the overall response of wheat to sulfur fertilization in diverse field environments, examining the effects based on soil texture and organic matter content. The greenhouse study investigated the effects of varying sulfur application rates and sources on protein concentration and grain yield and analyzed the relationship between sulfur and nitrogen concentrations in the grain. The meta-analysis showed overall positive effects of sulfur application on both protein concentration (2.1%) and grain yield (4.2%), with the magnitude of these effects varying based on soil texture and organic matter content. Sandy soils and soils with low organic matter content exhibited the most pronounced responses to sulfur fertilization. The greenhouse experiment revealed responses of both protein concentration and grain yield to increasing sulfur application rates, indicating an optimal rate beyond which additional sulfur may not provide further benefits. A strong positive correlation between sulfur and nitrogen concentrations in the grain highlighted their interdependence in wheat nutrition. These findings emphasize the importance of considering soil properties and the sulfur–nitrogen interaction when developing site-specific sulfur fertilization strategies for wheat. The results provide valuable insights for optimizing grain yield and protein concentration, contributing to more sustainable and efficient wheat production systems. Full article
34 pages, 21055 KiB  
Review
Polymeric and Crystalline Materials for Effective and Sustainable CO2 Capture
by David Gendron and Maria Zakharova
AppliedChem 2024, 4(3), 236-269; https://doi.org/10.3390/appliedchem4030016 (registering DOI) - 26 Jun 2024
Viewed by 110
Abstract
Carbon dioxide (CO2) is recognized as the primary cause of global warming due to its greenhouse potential. It plays a significant role in contributing to the emissions arising from a variety of anthropogenic activities, such as energy production, transportation, the construction [...] Read more.
Carbon dioxide (CO2) is recognized as the primary cause of global warming due to its greenhouse potential. It plays a significant role in contributing to the emissions arising from a variety of anthropogenic activities, such as energy production, transportation, the construction industry, and other industrial processes. Capturing and utilizing CO2 to mitigate its impact on the environment is, therefore, of significant importance. To do so, strategies such as net-zero strategies, deploying capture and storage technologies, and converting CO2 into useful products have been proposed. In this review, we focused our attention on the preparation and performance of polymeric and crystalline materials for efficient CO2 capture. More precisely, we examined MOFs, petroleum-based polymers (amine-based, polymeric ionic liquid, ionic polymer, conjugated macro/micro-cyclic polymer, and porous organic polymer) as well as bio-based polymers for CO2 capture. In brief, the present work aims to guide the reader on the available crafted polymeric and crystalline materials offering a promising avenue towards innovative carbon dioxide capture strategy. Full article
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18 pages, 1309 KiB  
Article
Research on Predictive Control Method of Pigsty Environment Based on Fuzzy Control
by Fengwu Zhu, Yuqing Zhang, Weijian Zhang, Tianshi Gao, Suyu Wang and Lina Zhou
Agriculture 2024, 14(7), 1004; https://doi.org/10.3390/agriculture14071004 - 26 Jun 2024
Viewed by 90
Abstract
At present, most of the environmental control systems of pigsties use direct control methods; when factors, such as temperature and humidity, exceed the set threshold value, the corresponding actuator is turned on for regulation. However, such methods have problems such as low control [...] Read more.
At present, most of the environmental control systems of pigsties use direct control methods; when factors, such as temperature and humidity, exceed the set threshold value, the corresponding actuator is turned on for regulation. However, such methods have problems such as low control accuracy, high energy consumption, and untimeliness. In order to save on energy consumption and improve control accuracy, this paper takes the predicted value, set value, and current detection value of the internal environment of a pigsty as input, and combines fuzzy control and direct control methods to realize the predictive control of the pigsty environment. The test results show that, compared with the direct control method, the fuzzy predictive control method can make fluctuations in the internal temperature and humidity of the pigsty less close to the set threshold value, while the ammonia concentration hardly exceeds the set threshold value. The results show that predictive control can more accurately control the internal environment of the pigsty and reduce energy costs by about 20%. Therefore, this method can provide scientific and effective environmental control methods for agricultural production processes, such as livestock breeding and greenhouse cultivation, in semi-confined spaces. Full article
12 pages, 674 KiB  
Article
What Is the Carbon Footprint of Adult Spinal Deformity Surgery?
by Hiroyuki Nakarai, Cole Kwas, Eric Mai, Nishtha Singh, Bo Zhang, John C. Clohisy, Robert K. Merrill, Anthony Pajak, Jerry Du, Gregory S. Kazarian, Austin C. Kaidi, Justin T. Samuel, Sheeraz Qureshi, Matthew E. Cunningham, Francis C. Lovecchio and Han Jo Kim
J. Clin. Med. 2024, 13(13), 3731; https://doi.org/10.3390/jcm13133731 - 26 Jun 2024
Viewed by 124
Abstract
Background/Objectives: While the economic cost of adult spinal deformity (ASD) surgery has been studied extensively, its environmental impact is unknown. The aim of this study is to determine the carbon footprint (CF) associated with ASD surgery. Methods: ASD patients who underwent [...] Read more.
Background/Objectives: While the economic cost of adult spinal deformity (ASD) surgery has been studied extensively, its environmental impact is unknown. The aim of this study is to determine the carbon footprint (CF) associated with ASD surgery. Methods: ASD patients who underwent > four levels of corrective surgery between 2017 and 2021 were included. The open group included a posterior-only, single-stage technique, while the minimally invasive surgery (MIS) group was defined as the use of lateral interbody fusion and percutaneous posterior screw fixation. The two groups were propensity-score matched to adjust for baseline demographic, surgical, and radiographic characteristics. Data on all disposables and reusable instruments, anesthetic gas, and non-gas medications used during surgery were collected from medical records. The CF of transporting, using, and disposing of each product and the footprint of energy use in operating rooms were calculated. The CF produced was evaluated using the carbon dioxide equivalent (CO2e), which is relative to the amount of CO2 with an equivalent global warming potential. Results: Of the 175 eligible patients, 15 pairs (65 ± 9 years, 47% female) were properly matched and analyzed for all variables. The average CF generated per case was 147.7 ± 37.3 kg-CO2e, of which 54% was attributable to energy used to sterilize reusable instruments, followed by anesthetic gas released into the environment (17%) and operating room air conditioning (15%). Conclusions: The CF generated during ASD surgery should be reduced using a multidisciplinary approach, taking into account that different surgical procedures have different impacts on carbon emission sources. Full article
(This article belongs to the Section Clinical Neurology)
30 pages, 2163 KiB  
Review
Geopolymer Cement in Pavement Applications: Bridging Sustainability and Performance
by Jacob O. Ikotun, Gbenga E. Aderinto, Makungu M. Madirisha and Valentine Y. Katte
Sustainability 2024, 16(13), 5417; https://doi.org/10.3390/su16135417 (registering DOI) - 26 Jun 2024
Viewed by 142
Abstract
Abstract: Sustainability and the quest for a more robust construction material cannot be divorced from each other. While Portland cement has revolutionized the construction sector, its environmental toll, particularly in greenhouse gas emissions and global warming, cannot be ignored. Addressing this dilemma [...] Read more.
Abstract: Sustainability and the quest for a more robust construction material cannot be divorced from each other. While Portland cement has revolutionized the construction sector, its environmental toll, particularly in greenhouse gas emissions and global warming, cannot be ignored. Addressing this dilemma requires embracing alternatives like geopolymer cement/geopolymer binder (GPC/GPB). Over the last few decades, considerable strides have been achieved in advancing GPC as a sustainable construction material, including its utilization in pavement construction. Despite these advances, gaps still exist in GPC optimal potential in pavement construction, as most studies have concentrated on specific attributes rather than on a comprehensive evaluation. To bridge this gap, this review adopts a novel, holistic approach by integrating environmental impacts with performance metrics. To set the stage, this review first delves into the geopolymer concept from a chemistry perspective, providing an essential broad overview for exploring GPC’s innovations and implications in pavement applications. The findings reveal that GPC not only significantly reduces greenhouse gas emissions and energy consumption compared to Portland cement but also enhances pavement performance. Further, GPC concrete pavement exhibits superior mechanical, durability, and thermal properties to ensure its long-term performance in pavement applications. However, challenges to GPC utilization as a pavement material include the variability of raw materials, the need for suitable hardeners, the lack of standardized codes and procedures, cost competitiveness, and limited field data. Despite these challenges, the process of geopolymerization presents GPC as a sustainable material for pavement construction, aligning with Sustainable Development Goals (SDGs) 3, 9, 11, and 12. Full article
10 pages, 1008 KiB  
Article
Pre-Harvest Chemical Compounds Influence Lily (Lilium × elegans) Leaf and Flower Indigenous Phenols, Flavonoids and Gibberellic Acid Levels
by Ahmed AlFayad and Yahia Othman
Int. J. Plant Biol. 2024, 15(3), 551-560; https://doi.org/10.3390/ijpb15030042 (registering DOI) - 26 Jun 2024
Viewed by 87
Abstract
The global cut flower industry, including lilies, represents a highly promising investment. Therefore, improving the quantity and quality of these commercially significant flower species is crucial. The objectives of this study were to (1) evaluate the influence of different pre-harvest chemical compounds on [...] Read more.
The global cut flower industry, including lilies, represents a highly promising investment. Therefore, improving the quantity and quality of these commercially significant flower species is crucial. The objectives of this study were to (1) evaluate the influence of different pre-harvest chemical compounds on endogenous GA3, phenol, flavonoids and total antioxidants levels on the leaf and petals parts of Longiflorum-Asiatic (Lilium × elegans cv. Cevennes, yellow) lily and to (2) assess the effect of these compound on the flower quality component. The study was conducted over two cycles in both greenhouse and laboratory settings. Lily bulbs were transplanted into 10 L pots and grown for 70 days. Treatments were applied by spraying twice with a five-day interval on the flowers still on the plants and not yet fully opened. The treatments included 8-hydroxyquinoline sulfate (8HQS) at 100, 200, and 400 mg L−1; salicylic acid (SA) at 100 and 200 mg L−1; SmartFresh™ at 1 and 2 mg L−1; Harvista™ at 150 mg L−1; GA₃ at 50 mg L−1; and a control (water). The lily stems were harvested when one of the flowering buds began to open but was not fully opened. A post-harvest assessment was conducted in the laboratory at room temperature (20 ± 2 °C). The results showed that the lily leaf had a much higher endogenous concentration of GA3 (256%) and lower concentrations of total phenols (22%), flavonoids (28%), and antioxidant activity (14%) when compared to flower petals. In addition, the foliar application of flower preservative compounds one week before harvesting significantly improved the endogenous levels of GA3, total phenols, flavonoids, and antioxidants activity, especially SmartFresh™ at rate of 1 mg L−1. In terms of flower quality, SmartFresh™, at rate of 1 mg L−1, and 8-HQS, at rate of 200, had consistently higher vase lives compared to the control treatment across the two experimental cycles. Compared to the control, SmartFresh™ (the post-harvest ethylene control) increased the vase life of lily flowers by 35% at cycle 1 and 31% at cycle 2 while 8-HQS, at rate of 200 mg L−1, increased the vase life by 21% and 15% at cycles 1 and 2, respectively. However, no significant effect was found in the petal flower color coordinates (L*, a* and b*) across the treatments. Overall, the foliar application of preservative compounds (such as SmartFresh™) at the pre-harvest stage potentially stimulates the endogenous levels of GA3, total phenols, flavonoids, and antioxidants activity, leading to better improvements in post-harvest flower quality, specifically vase life. Full article
(This article belongs to the Section Plant Biochemistry and Genetics)
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26 pages, 1875 KiB  
Article
Enhancing Electric Shuttle Bus Efficiency: A Case Study on Timetabling and Scheduling Optimization
by Kayhan Alamatsaz, Frédéric Quesnel and Ursula Eicker
Energies 2024, 17(13), 3149; https://doi.org/10.3390/en17133149 - 26 Jun 2024
Viewed by 111
Abstract
As transit authorities increasingly adopt electric buses (EBs) to mitigate air quality concerns and greenhouse gas emissions, new challenges arise in bus scheduling and timetabling. Unlike traditional buses, EBs face operational obstacles due to their shorter range and extended charging times. Existing mathematical [...] Read more.
As transit authorities increasingly adopt electric buses (EBs) to mitigate air quality concerns and greenhouse gas emissions, new challenges arise in bus scheduling and timetabling. Unlike traditional buses, EBs face operational obstacles due to their shorter range and extended charging times. Existing mathematical optimization models for operation planning of traditional buses must be revised to address these unique characteristics of EBs. This study introduces a new approach to integrate timetabling and bus scheduling to enhance the level of service and minimize operational costs, using a case study of a University shuttle bus service in Montreal, Canada. The level of service will be enhanced by reducing students waiting time and improving their in-vehicle comfort through seat availability. The scheduling aspect seeks to reduce the total operational costs, which include travel, electricity consumption, and usage costs of EBs. The proposed algorithm calculates the waiting time and seat availability for different headway values and addresses the scheduling problem using a mixed-integer linear programming (MILP) model with an arc-based approach, solved using the Cplex Optimization Studio software version 12.8. A normalized weighted sum technique is then applied to select the optimal headway, balancing waiting time, seat availability, and operational costs. The effectiveness of our approach was tested through a case study of Concordia University’s shuttle bus service. Comparative analysis of the current and proposed schedules shows that our approach significantly improves service quality by decreasing waiting times and increasing seat availability while optimizing cost-effectiveness compared to the existing timetable of the Concordia shuttle bus. The proposed approach ensures a smooth transition to a fully electric transit system for shuttle bus services. Full article
(This article belongs to the Section E: Electric Vehicles)
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3 pages, 1000 KiB  
Correction
Correction: Peng et al. A Comparison of Greenhouse Gas Emission Patterns in Different Water Levels in Peatlands. Water 2024, 16, 985
by Chengcheng Peng, Hengfei Li, Nan Yang and Mingzhi Lu
Water 2024, 16(13), 1801; https://doi.org/10.3390/w16131801 - 26 Jun 2024
Viewed by 80
Abstract
There were errors in the original publication [...] Full article
(This article belongs to the Special Issue Restoration of Wetlands for Climate Change Mitigation)
23 pages, 3802 KiB  
Article
Eco-Efficiency of Pellet Production from Dedicated Poplar Plantations
by Giulio Sperandio, Alessandro Suardi, Andrea Acampora and Vincenzo Civitarese
Energies 2024, 17(13), 3137; https://doi.org/10.3390/en17133137 - 26 Jun 2024
Viewed by 119
Abstract
Biomass, due to its neutrality in terms of greenhouse gas emissions into the atmosphere during its life cycle, is considered an interesting renewable source for energy production as an alternative to the use of more polluting fossil fuels. Among the different wood fuels, [...] Read more.
Biomass, due to its neutrality in terms of greenhouse gas emissions into the atmosphere during its life cycle, is considered an interesting renewable source for energy production as an alternative to the use of more polluting fossil fuels. Among the different wood fuels, pellets are convenient for use in dedicated stoves, and pellet heating systems have a high energy efficiency. The aim of this work was to estimate the economic and global warming potential (GWP100a) generated along the thermal energy supply chain of wood pellets, starting from the production of raw biomass from dedicated poplar cultivations and ending with the use of pellets in stoves by the end-user to produce thermal energy and ash. The Eco-Efficiency Indicator (EEI) was used to link the economic and environmental performance for eight proposed scenarios, obtained by combining different levels of mechanisation for poplar harvesting and wood biomass management before arrival at the pellet plant. For the thermal energy produced by the poplar wood pellet, the GWP100a ranged from 1.5 × 10−2 to 2.1 × 10−2 kg CO2−eq MJ−1 for three-year-old plantations and from 1.9 × 10−2 to 2.4 × 10−2 kg CO2−eq MJ−1, for six-year-old plantations. In terms of eco-efficiency of the baseline scenario (EEIb), the most favourable scenarios remain those linked to the use of biomass from three-year-old poplar plantations, with EEIb values ranging from 0.31 to 0.60 € kgCO2−eq−1, compared to from 0.29 to 0.36 € kgCO2−eq−1 for pellets obtained from biomass produced from six-year-old poplar plantations. In terms of the Global Eco-Efficiency Indicator (EEIg), which also takes into account the positive effect on the reduction of greenhouse gases due to the storage of carbon in the soil by the plantations and the reduction of emissions from avoided fossil fuels, the most favourable scenarios remain those linked to the use of biomass from three-year-old poplar plantations, with EEIg values that vary in the range of 0.60 ÷ 1.04 € kgCO2−eq−1, compared to 0.55 ÷ 0.62 € kg CO2−eq−1 for thermal energy obtained using biomass from six-year-old poplar plantations. Full article
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13 pages, 527 KiB  
Review
Animal Behaviour Packs a Punch: From Parasitism to Production, Pollution and Prevention in Grazing Livestock
by Lesley A. Smith, Naomi J. Fox, Glenn Marion, Naomi J. Booth, Alex M. M. Morris, Spiridoula Athanasiadou and Michael R. Hutchings
Animals 2024, 14(13), 1876; https://doi.org/10.3390/ani14131876 - 25 Jun 2024
Viewed by 272
Abstract
Behaviour is often the fundamental driver of disease transmission, where behaviours of individuals can be seen to scale up to epidemiological patterns seen at the population level. Here we focus on animal behaviour, and its role in parasite transmission to track its knock-on [...] Read more.
Behaviour is often the fundamental driver of disease transmission, where behaviours of individuals can be seen to scale up to epidemiological patterns seen at the population level. Here we focus on animal behaviour, and its role in parasite transmission to track its knock-on consequences for parasitism, production and pollution. Livestock face a nutrition versus parasitism trade-off in grazing environments where faeces creates both a nutritional benefit, fertilizing the surrounding sward, but also a parasite risk from infective nematode larvae contaminating the sward. The grazing decisions of ruminants depend on the perceived costs and benefits of the trade-off, which depend on the variations in both environmental (e.g., amounts of faeces) and animal factors (e.g., physiological state). Such grazing decisions determine the intake of both nutrients and parasites, affecting livestock growth rates and production efficiency. This impacts on the greenhouse gas costs of ruminant livestock production via two main mechanisms: (1) slower growth results in longer durations on-farm and (2) parasitised animals produce more methane per unit food intake. However, the sensitivity of behaviour to host parasite state offers opportunities for early detection of parasitism and control. Remote monitoring technology such as accelerometers can detect parasite-induced sickness behaviours soon after exposure, before impacts on growth, and thus may be used for targeting individuals for early treatment. We conclude that livestock host x parasite interactions are at the centre of the global challenges of food security and climate change, and that understanding livestock behaviour can contribute to solving both. Full article
(This article belongs to the Special Issue Interrelationships between Animal Behaviors and Control of Diseases)
21 pages, 1392 KiB  
Article
The Effects of Different Combinations of Cattle Organic Soil Amendments and Copper on Lettuce (cv. Rufus) Plant Growth
by Chiara De Carolis, Valentina Iori, Alessandra Narciso, Davide Gentile, Barbara Casentini, Fabrizio Pietrini, Paola Grenni, Anna Barra Caracciolo and M. Adelaide Iannelli
Environments 2024, 11(7), 134; https://doi.org/10.3390/environments11070134 - 25 Jun 2024
Viewed by 221
Abstract
In modern agricultural production, cattle manure waste recovery is considered as a sustainable approach to agricultural waste management, reducing environmental pollution and chemical fertilizer use. This study aimed to investigate the effects of manure and digestate derived from a pilot-scale livestock waste-recycling system, [...] Read more.
In modern agricultural production, cattle manure waste recovery is considered as a sustainable approach to agricultural waste management, reducing environmental pollution and chemical fertilizer use. This study aimed to investigate the effects of manure and digestate derived from a pilot-scale livestock waste-recycling system, in combination with a low copper concentration as a fungicide, on the physiological response of lettuce cv Rufus (Lactuca sativa L.) plants and the associated soil microbiome. A five-week microcosm experiment was conducted in a greenhouse under environmental conditions. Lettuce plant performance was assessed in terms of biomass, leaf area index, photosynthetic activity, chlorophyll measurements, lipid peroxidation, total phenolic content, and nutrient uptake. The results suggested that incorporating digestate into the potting soil mix significantly enhanced crop yields compared to the control and manure treatments. The soil microbial activity increased in the presence of fertilizers, improving the soil chemical and biological properties. The addition of copper negatively affected the growth and physiological performance of the lettuce plants under both the control and manure-treated conditions, except for those grown in the presence of digestate, where copper accumulation was reduced. These findings highlight the potential of growing horticultural crops using organic fertilization through livestock waste anaerobic digestate, establishing a waste-to-food recycling system. Full article
11 pages, 807 KiB  
Article
In Vitro Micropropagation of the Vulnerable Chilean Endemic Alstroemeria pelegrina L.
by Francesca Guerra, Ricardo Cautín and Mónica Castro
Horticulturae 2024, 10(7), 674; https://doi.org/10.3390/horticulturae10070674 (registering DOI) - 25 Jun 2024
Viewed by 132
Abstract
The Chilean rhizomatous geophyte Alstroemeria pelegrina (A. pelegrina), a species endemic to the Coquimbo (31°45′ S) and Valparaíso (33°12′ S) regions, is currently classified as vulnerable and experiencing population decline due to loss of habitat. This heightened threat underscores the need [...] Read more.
The Chilean rhizomatous geophyte Alstroemeria pelegrina (A. pelegrina), a species endemic to the Coquimbo (31°45′ S) and Valparaíso (33°12′ S) regions, is currently classified as vulnerable and experiencing population decline due to loss of habitat. This heightened threat underscores the need to develop effective mass propagation techniques to support its conservation efforts. Consequently, the present study aimed to establish an optimized in vitro propagation protocol tailored specifically for A. pelegrina to facilitate its large-scale propagation and promote the preservation of this vulnerable geophyte. In our experiment, explants obtained from in vitro germination were used. These explants were then cultured on a Murashige and Skoog (MS) medium solidified with agar (6 g L−1) and supplemented with 2.22 μM 6-Benzylaminopurine (BAP) and 30 g L−1 sucrose. The results indicated an average of 4.6 new shoots produced per initial explant. The implementation of light-emitting diode (LED) illumination with a red:blue ratio of 3:1 and 2.22 μM BAP resulted in an average shoot length of 6.2 cm. For rhizome induction, the addition of either 5.37 μM 1-naphthaleneacetic acid (NAA) or 5.37 μM indole-3-butyric acid (IBA) resulted in average rhizome lengths of 1.9 cm and 1.7 cm, respectively, with fresh weights of the vitroplants ranging from 2.9 g to 3.1 g, and rooting percentages between 100% and 96%, respectively. Notably, the survival rate of rooted plants obtained through in vitro propagation was 90% after a 4-week acclimatization period in a cold greenhouse, indicating the efficacy of the developed protocol for mass propagation and conservation efforts of this vulnerable geophyte species. Full article
(This article belongs to the Special Issue Tissue Culture and Micropropagation Techniques of Horticultural Crops)
12 pages, 872 KiB  
Article
The Effects of the Co-Application of MCPA Herbicide and Urea on Grass Rhizosphere Microcosms
by Marco A. Campos, Graciela Palma, Carlos Faundez and Sebastian Elgueta
Agronomy 2024, 14(7), 1366; https://doi.org/10.3390/agronomy14071366 - 25 Jun 2024
Viewed by 144
Abstract
Background: Urea fertilizer and MCPA herbicide are widely used agrochemicals in pastures. Even though urea hydrolysis impacts soil pH, potentially affecting MCPA dissipation, little is known about the effects of their co-application into the rhizosphere. Hence, we aimed to analyze the dynamics of [...] Read more.
Background: Urea fertilizer and MCPA herbicide are widely used agrochemicals in pastures. Even though urea hydrolysis impacts soil pH, potentially affecting MCPA dissipation, little is known about the effects of their co-application into the rhizosphere. Hence, we aimed to analyze the dynamics of urea transformation and MCPA dissipation when both are co-applied to the soil. Methods: A greenhouse experiment was conducted with a planted control and treatments incorporating urea and/or MCPA. Subsequently, pH changes, urea transformation into N‑NH4+ and N‑NO3, the enzymatic activity of urease and dehydrogenase, and MCPA dissipation were monitored for 30 d. Results: Urea application induced a significant (p < 0.05) pH change, production of N‑NH4+ (from 50 and 250 mg kg−1) and N‑NO3 (from 206 to 347 mg kg−1), and urease (from 12 to 35 µmol N-NH4⁺g⁻1 h⁻1) and dehydrogenase (from 0.5 to 2.5 mg TPF g−1 h−1) activities. Urea also decelerated MCPA dissipation in the latter half of the experiment, whereas MCPA reduced urease activity when urea and herbicide were co-applied. Conclusions: Urea was the primary factor modifying the properties of the rhizosphere by stimulating the activity of microbial enzymes, shaping the pH changes during its mineralization, and decelerating MCPA dissipation. MCPA did not reduce urea mineralization but slowed urease activity, constituting an insight that requires further study. Full article
(This article belongs to the Section Soil and Plant Nutrition)
30 pages, 2714 KiB  
Article
Dynamic Simulation and Optimization of Off-Grid Hybrid Power Systems for Sustainable Rural Development
by Wajahat Khalid, Qasim Awais, Mohsin Jamil and Ashraf Ali Khan
Electronics 2024, 13(13), 2487; https://doi.org/10.3390/electronics13132487 - 25 Jun 2024
Viewed by 243
Abstract
This paper analyzes dynamic modeling for rural HPS to address GHG emissions’ environmental impact on floods and climate change. The aim is to integrate renewable energy sources, such as solar energy, with traditional generators to mitigate emissions and enhance energy access in rural [...] Read more.
This paper analyzes dynamic modeling for rural HPS to address GHG emissions’ environmental impact on floods and climate change. The aim is to integrate renewable energy sources, such as solar energy, with traditional generators to mitigate emissions and enhance energy access in rural communities in Pakistan. The system is designed using a DC-DC converter, MPPT, LCL filter, and a DC-AC inverter. Utilizing software tools like PVsyst 7.4 and HOMER Pro-3.18.1, the study evaluates system sizing, energy consumption patterns, and optimization strategies tailored to site-specific data. The expected results include a reliable, environmentally friendly hybrid power system capable of providing consistent electricity to rural areas. The analysis of a connected load of 137.48 kWh/d and a peak load of 33.54 kW demonstrates the system’s promise for reliable electricity with minimal environmental impact. The estimated capital cost of USD 102,310 and energy generation at USD 0.158 per unit underscores economic feasibility. Dynamic modeling and validation using HIL examine the system’s behavior in response to variations in solar irradiance and temperature, offering insights into operational efficiency and reliability. The study concludes that the hybrid power system is scalable for rural energy access, which is a practical solution achieving a 100% renewable energy fraction, significantly contributing to emission reduction and promoting sustainable energy practices. Full article
(This article belongs to the Special Issue Modeling and Design of Power Converters)
17 pages, 1270 KiB  
Article
Sorption of Iodine on Biochar Derived from the Processing of Urban Sludge and Garden Waste at Different Pyrolysis Temperatures
by Bing Bai, Qingyang Liu, He Li, Dan Liu, Haichao Wang, Chengliang Zhang, Zheng Yang and Jingjing Yao
Molecules 2024, 29(13), 3007; https://doi.org/10.3390/molecules29133007 - 25 Jun 2024
Viewed by 153
Abstract
The United Nations proposed the Sustainable Development Goals with the aim to make human settlements in cities resilient and sustainable. The excessive discharge of urban waste including sludge and garden waste can pollute groundwater and lead to the emission of greenhouse gases (e.g., [...] Read more.
The United Nations proposed the Sustainable Development Goals with the aim to make human settlements in cities resilient and sustainable. The excessive discharge of urban waste including sludge and garden waste can pollute groundwater and lead to the emission of greenhouse gases (e.g., CH4). The proper recycling of urban waste is essential for responsible consumption and production, reducing environmental pollution and addressing climate change issues. This study aimed to prepare biochar with high adsorption amounts of iodine using urban sludge and peach wood from garden waste. The study was conducted to examine the variations in the mass ratio between urban sludge and peach wood (2/1, 1/1, and 1/2) as well as pyrolysis temperatures (300 °C, 500 °C, and 700 °C) on the carbon yield and adsorption capacities of biochar. Scanning electron microscopy, Brunauer–Emmett–Teller analysis, Fourier transform infrared spectrometry, powder X-ray diffraction, and elemental analysis were used to characterize the biochar produced at different pyrolysis temperatures and mass ratios. The results indicate that the carbon yield of biochar was found to be the highest (>60%) at a pyrolysis temperature of 300 °C across different pyrolysis temperatures. The absorbed amounts of iodine in the aqueous solution ranged from 86 to 223 mg g−1 at a mass ratio of 1:1 between urban sludge and peach wood, which were comparably higher than those observed in other mass ratios. This study advances water treatment by offering a cost-effective method by using biochar derived from the processing of urban sludge and garden waste. Full article
(This article belongs to the Section Green Chemistry)
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