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Multiple studies have investigated the use of steel, synthetic fibers, and natural fibers to reduce plastic shrinkage cracks in concrete, which are mostly caused by water evaporation from the surface of the material. This review used original published research articles from the Web of Science and Scopus database to evaluate the performance and relationship between the fiber volume, aspect ratio, compressive strength, and plastic shrinkage cracking. This review also discussed the most widely used technique for evaluating plastic shrinkage cracking, the ASTM C 1579, with two bottom restraints and a central stress riser to induce cracking, and its modified version with additional reinforcement for further restraining the ASTM C 1579 mold. Longer fibers function better than shorter fibers because of their larger surface area, which allows them to bridge fissures. It was also observed that crack initiation time is delayed when fibers are added to concrete. In addition, as the volume proportion of the fibers increased, the plastic shrinkage cracks decreased, but the compressive strength declined. Furthermore, the volume fraction of the fibers had a greater effect on reducing cracking than the aspect ratio. It was also concluded that a fiber volume inclusion below 1% is best. Full article

Over recent decades, natural and artificial colloids, as well as nanoparticles, have been increasingly used in various applications. Consequently, with this rising consumption, surface and subsurface environments are more exposed to these particles. The presence of these particles and the colloid-facilitated transport of microorganisms, the interactions between dissolved contaminants and mobile colloids in porous media, and the fate and transport of colloids through groundwater—one of the primary sources of water supply for human societies—have attracted extensive research. This study investigates the performance of several image processing methods in the field of colloid detection, which is a prerequisite for the subsequent steps in porous media research. We employed four different categories of image processing approaches on microscopy images—segmentation-based methods, background-detection-based methods, filter-based methods, and morphology-based methods—to conduct the detection process of colloids. Eight methods were applied and subsequently analyzed in terms of their drawbacks and advantages to determine the best ones in this domain. Finally, we proposed an ensemble approach that leverages the strengths of the three best methods using a majority vote to detect colloids more accurately. In experiments, Precision, Recall, F-measure, and TCR criteria were considered as evaluation tools. Experimental results demonstrate the high accuracy of image processing methods in recognizing colloids. Among all these methods, morphology-based methods were the most successful, achieving the best detection performance and improving the limited distinguishing features of small colloids. Moreover, our ensemble approach, achieving perfect scores across all evaluation criteria, highlights its superiority compared with other detection methods. Full article

The coffee industry is developing rapidly in the world, and the use of coffee filtration nonwovens (CFNs) is becoming more and more extensive; however, there is a lack of standards and research for its production and trade, and the quality of related products on the market is uneven at present. Here, eight double-layer composite coffee filtration nonwovens (D-LCCFNs) were prepared by using 5 g/m² and 10 g/m² polypropylene (PP) melt-blown nonwovens (MNs), 20 g/m² PP spunbonded nonwovens and 20 g/m² viscose/ES fiber chemically bonded nonwovens, and the physical properties, morphology and the filtration effect of coffee and purified water for the prepared samples were tested. It was found that the surface density of the microfiber layer (MNs) in the D-LCCFNs was negatively correlated with the coffee filtration rate; when the microfiber layer in the D-LCCFNs was in direct contact with the coffee, the liquid started to drip later, and the filtration rate of the coffee was slower; the filtration rate of the samples with the viscose/ES chemically bonded nonwovens was very fast. However, the samples without viscose/ES fibers basically did not filter pure water much, but they could filter out the coffee liquid normally, and the samples’ hydrophilicity increased significantly after filtering coffee. Full article

Shale formations present significant challenges to traditional drilling fluids due to fluid infiltration, cuttings dispersion, and shale swelling, which can destabilize the wellbore. While oil-based drilling fluids (OBM) effectively address these concerns about their environmental impact, their cost limits their widespread use. Recently, nanomaterials (NPs) have emerged as a promising approach in drilling fluid technology, offering an innovative solution to improve the efficiency of water-based drilling fluids (WBDFs) in shale operations. This study evaluates the potential of utilizing modified silica nanocomposite and graphene nanopowder to formulate a nanoparticle-enhanced water-based drilling fluid (NP-WBDF). The main objective is to investigate the impact of these nanoparticle additives on the flow characteristics, filtration efficiency, and inhibition properties of the NP-WBDF. In this research, a silica nanocomposite was successfully synthesized using emulsion polymerization and analyzed using FTIR, PSD, and TEM techniques. Results showed that the silica nanocomposite exhibited a unimodal particle size distribution ranging from 38 nm to 164 nm, with an average particle size of approximately 72 nm. Shale samples before and after interaction with the graphene nanopowder WBDF and the silica nanocomposite WBDF were analyzed using scanning electron microscopy (SEM). The NP-WBM underwent evaluation through API filtration tests (LTLP), high-temperature/high-pressure (HTHP) filtration tests, and rheological measurements conducted with a conventional viscometer. Experimental results showed that the silica nanocomposite and the graphene nanopowder effectively bridged and sealed shale pore throats, demonstrating superior inhibition performance compared to conventional WBDF. Post adsorption, the shale surface exhibited increased hydrophobicity, contributing to enhanced stability. Overall, the silica nanocomposite and the graphene nanopowder positively impacted rheological performance and provided favorable filtration control in water-based drilling fluids. Full article

Biochar return to the field has been widely explored, but there is a problematic disconnect between biochar preparation and biochar return to the field. In this study, soybean straw is used as a raw material and is sieved into two components: 60-mesh (0.250 mm) and 110-mesh (0.130 mm). Four kinds of biochar were obtained by pyrolysis under the condition of no heat preservation and heat preservation for 60 min. The biochar was applied to the soil, and the effects of biochar on soil and capsicum growth were analyzed by Spearman correlation. Compared with the control group, soil pH, soil electrical conductivity, and soil organic matter decomposition were increased by 0.58, 101 μs/cm, and 9.48%, respectively. The fruit quantity, plant height, water, fat, soluble solid, and titrable acidity of capsicum were increased by 1, 0.55, 0.08, 0.62, 0.67, and 0.7 times, respectively. Spearman correlation analysis showed that soil properties and capsicum growth were most affected by biochar’s specific surface area (SSA). Therefore, increasing the biomass mesh number and heat preservation time is beneficial to increasing the SSA of biochar and facilitating the return of biochar to the field and the best preparation conditions are 110-mesh soybean straw biomass pyrolysis and heat preservation for 60 min. Full article

Biodegradable polymers and their blends have been advised as an eco-sustainable solution; however, the generation of microplastics (MPs) from their degradation in aquatic environments is still not fully grasped. In this study, we investigated the formation of bio-microplastics (BMPs) and the changes in the physicochemical properties of blown packaging films based on polylactic acid (PLA), polybutylene succinate (PBS) and a PBS/PLA 70/30 wt% blend after degradation in different aquatic media. The tests were carried out in two temperature/light conditions to simulate degradation in either warm water, under sunlight exposure (named Warm and Light—W&L), and cold deep water (named Cold and Dark—C&D). The pH changes in the aqueous environments were evaluated, while the formed BMPs were analyzed for their size and shape alongside with variations in polymer crystallinity, surface and mechanical properties. In W&L conditions, for all the films, the hydrolytic degradation led to the reorganization of the polymer crystalline phases, strong embrittlement and an increase in hydrophilicity. The PBS/PLA 70/30 blend exhibited increased resistance to degradation with respect to the neat PLA and PBS films. In C&D conditions, no microparticles were observed up to 12 weeks of degradation. Full article

In order to optimize the application of desert sand autoclaved bricks in rural construction in Xinjiang, this study focuses on the research and development of MU15-grade desert sand autoclaved bricks. Experimental investigations were conducted to examine the relationship between the water absorption rate of desert sand autoclaved bricks and the duration of water absorption while analyzing the impact of the water absorption rate on the compressive strength of these bricks. Additionally, experimental research was carried out to evaluate the appearance, compressive strength, and pore structure of autoclaved bricks after sulfate erosion. The results indicate the following. (1) With an increasing immersion time, the water absorption rate of desert sand-based autoclaved bricks initially rises and then declines, reaching approximately 14.74% when immersed for 4 h, which is close to the saturation water absorption rate. (2) The compressive strength of desert sand-based autoclaved bricks gradually decreases with an increasing water absorption rate, reaching its lowest point when saturation is attained, with a strength loss rate of approximately 33.18%. (3) Finally, after sulfate erosion, cracks and detachment appear on the surface of desert sand-based autoclaved bricks, and these cracks extend and propagate with the continuous accumulation of eroded products. Simultaneously, this process leads to an increase in the proportion of harmful pores by 0.96%, thereby causing a deterioration in strength. Through data analysis, a decay curve of the compressive strength erosion coefficient of desert sand-based autoclaved bricks with the number of sulfate erosion cycles was established, with good accuracy. This study provides theoretical references and technical support for the performance characteristics of desert sand-based autoclaved bricks and their application in rural construction in Xinjiang. Full article

The variation in the Asian summer monsoon anticyclone (ASMA) has long been of interest due to its effects on the weather and climate, as well as the vertical transport of pollutants in South Asia and East Asia. This study employs composite analysis to investigate the differences in the influences of sea surface temperature (SST) anomalies in the Western Pacific (WP) and the Indian Ocean (IO) on the ASMA and water vapor in the upper troposphere during summer. The underlying physical mechanisms were further explored. The results indicate that the warm SSTs in the WP have a greater impact on the intensity of the ASMA than those in the IO in summer. On the contrary, the cold SSTs in the IO have a greater impact on intensity of the ASMA than those in the WP in summer. The difference in the impact of SSTs in the WP and IO on the boundaries of the ASMA is relatively small. During positive SST anomalies in the WP, the increase in tropospheric temperature in South Asia and the strengthening of Walker circulation in the WP both contribute to the enhancement of the ASMA. The variations in tropospheric temperature and Walker circulation caused by positive SST anomalies in the IO are similar to those in the WP, except that the rising branch of the Walker circulation is located in the central and western IO. The decrease in SST in the WP region causes insignificant changes in the ASMA. During the cold SST period in the IO, the significant decrease in tropospheric temperature and the weakening of the Walker circulation in the IO region lead to a significant decrease in the intensity of the ASMA at the southern ASMA. When the SST in the WP and IO regions is warmer, the high value centers of water vapor in the troposphere generally coincide with the high value centers of temperature, accompanied by enhanced convection, significantly increasing the water vapor south of the ASMA. The anomalous sinking movement in the Western Pacific leads to relatively small changes in water vapor from the near-surface to 150 hPa over the southeast of the ASMA. Full article

Titanium alloys are difficult to machine and have poor tribological properties. Nanoparticles have good cooling and lubricating properties, which can be used in metal cutting fluid. The lubrication characteristics of the two-dimensional materials Ti₃C₂T_X MXene and graphene oxide in water-based fluid for titanium alloys were comparatively investigated in this paper. Graphene oxide had smaller friction coefficients and wear volume than Ti₃C₂T_X MXene nanofluid. As to the mechanism, MXene easily formed TiO₂ for the tribo-chemical reaction, which accelerated wear. Moreover, GO nanofluid can form a more uniform and stable friction layer between the frictional interface, which reduces the friction coefficient and decreases the adhesive wear. The effects of different surfactants on the lubricating properties of MXene were further investigated. It was found that the cationic surfactant Hexadecyl trimethyl ammonium chloride (1631) had the lowest friction coefficient and anti-wear properties for the strong electrostatic attraction with MXene nanoparticles. The results of this study indicate that 2D nanoparticles, especially graphene oxide, could improve the lubricating properties of titanium alloys. It provides insight into the application of water-based nanofluids for difficult-to-machine materials to enhance surface quality and cutting efficiency. The developed nanofluid, which can lubricate titanium alloys, effectively has very broad applications in prospect. Full article

With the increasing demand for marine biosensing and water–air collaborative rescue in national production and life, establishing a robust cross-medium communication link has become one of the hotspots. Among them, microwave acoustic cross-medium uplink communication technology has been widely studied for its advantages of being able to be used all day and in all weather, there being no need for relay, and having high concealment. The principle is to extract the frequency of the acoustic water surface waves from the phase history of the radar echoes. However, wave interference can cause discontinuity of the phase history, resulting in difficulty in extracting the acoustic water surface waves and an increase in bit error rate (BER). This article analyses the reasons for the discontinuity of phase history and innovatively proposes a method for extracting acoustic water surface waves based on phase compensation. The discontinuity points of the phase history are compensated based on whether the range bin changes. Then, low-frequency water surface fluctuations and discontinuity points are filtered out through second-order differential joint outlier removal, which can effectively reduce the influence of phase history discontinuity on time–frequency analysis and communication decoding. The effectiveness of the proposed method was verified through simulations and experiments. The experimental results indicate that the BER of the proposed method is 25% of that of the Wavelet–Kalman Filtering method. The proposed method provides a new approach for microwave acoustic cross-medium uplink communication. Full article

Like many coastal lagoons in several countries, the “Navío Quebrado” lagoon (La Guajira, Colombia) is a very delicate and precious environment; indeed, it is a nationally recognized Flora and Fauna Sanctuary. Several factors, including climate change, are threatening its existence because of changes in the governing hydro-morphological and biological processes. Certainly, the first step to addressing this problem is to understand its hydrological behavior and to be able to replicate, via simulation, its recent history before inferring likely futures. These potential futures will be marked by changes in the water input by its tributary, the Camarones River, and by modified water exchange with the sea, according to a foreseen sea level rise pattern, as well as by a different evaporation rate from the free surface, according to temperature changes. In order to achieve the required ability to simulate future scenarios, data on the actual behavior have to be gathered, i.e., a monitoring system has to be set up, which to date is non-existent. Conceptually, designing a suitable monitoring system is not a complex issue and seems easy to implement. However, the environmental, socio-cultural, and socio-economic context makes every little step a hard climb. An extremely simple—almost “primitive”—monitoring system has been set up in this case, which is based on very basic measurements of river flow velocity and water levels (river, lagoon, and sea) and the direct participation of local stakeholders, the most important of which is the National Park unit of the Sanctuary. All this may clash with the latest groovy advances of science, such as in situ automatized sensors, remote sensing, machine learning, and digital twins, and several improvements are certainly possible and desirable. However, it has a strong positive point: it provides surprisingly reasonable data and operates at almost zero additional cost. Several technical difficulties made this exercise interesting and worthy of being shared. Its novelty lies in showing how old, simple methods may offer a working solution to new challenges. This humble experience may be of help in several other similar situations across the world. Full article

Starch-based pH-sensing films with bacterial nanocellulose (BNC) and red cabbage anthocyanins (RCA) as active components were investigated in this research. Their structural, physical, surface and colorimetric properties were analyzed, mainly as a function of BNC concentration. The aim of the research was to relate the changes in the intermolecular interactions between the components of the films (starch, anthocyanins and BNC) to the physical, surface and colorimetric properties that are important for the primary intended application of the produced films as pH indicators in smart packaging. The results showed that maize starch (MS) was more suitable as a matrix for the stabilization of anthocyanins compared to potato starch (PS). PS-based films showed a lower value of water contact angle than MS-based films, indicating stronger hydrophilicity. The swelling behavior results indicate that the concentrations of BNC in MS-based films (cca 10%) and the concentration of about 50% BNC in PS-based films are required if satisfactory properties of the indicator in terms of stability in a wet environment are to be achieved. The surface free energy results of PS-based films with BNC were between 62 and 68 mJ/m² and with BNC and RCA between 64 and 68 mJ/m²; for MS-based films, the value was about 65 mJ/m² for all samples with BNC and about 68 mJ/m² for all samples with BNC and RCA. The visual color changes after immersion in different buffer solutions (pH 2.0–10.5) showed a gradual transition from red/pink to purple, blue and green for the observed samples. Films immersed in different buffers showed lower values of 2 to 10 lightness points (CIE L*) for PS-based films and 10 to 30 lightness points for MS-based films after the addition of BNC. The results of this research can make an important contribution to defining the influence of intermolecular interactions and structural changes on the physical, surface and colorimetric properties of bio-based pH indicators used in smart packaging applications. Full article

Plastic greenhouses play an important role in vegetable cultivation in China. While evaluations have attributed perfluoroalkyl acid contamination in greenhouse vegetables primarily to irrigation water, the potential contribution from greenhouse plastic films has consistently been overlooked, despite PFAAs’ long-standing use as anti-fogging agents. In this study, a comprehensive assessment of PFAA contamination was conducted in greenhouses at the Shouguang vegetable base in China, based on extensive environmental and crop sample collection, followed by analysis using LC-MS/MS. PFAAs are still used in greenhouse plastic film, and their migration to the surface water mist and the air inside the greenhouse was also observed. Elevated levels of PFAA pollution were found near the corner areas of greenhouses with longer service times, leading to further pollution of the soil and nearby vegetables. This is considered as the primary source which may have been caused by PFAAs migrating with condensation from the plastic film and accumulating for decades. However, polluted irrigation water still remains the dominate source of PFAAs in other areas inside the greenhouse. Based on our analysis, we conclude that PFAAs present in plastic films could be the primary contaminant source for vegetables in specific zones. This underscores the urgent need for heightened vigilance towards environmental pollution within agricultural facilities, which currently represent the most prevalent mode of intensive vegetable cultivation in China. Full article

This paper examines the application of non-synthetic particle suspensions as a support medium for the additive manufacturing of complex doubly curved ceramic shells with overhangs between 0° and 90° using clay paste. In this method, the build-up material is injected within a constant volume of air-permeable particle suspension. As the used clay paste does not solidify right after injection, the suspension operates like a support medium and enables various print path strategies. Different non-synthetic suspension mixtures, including solid and flexible components such as quartz sand, refractory clay, various types of wood shavings, and cotton flocks, were evaluated for their ability to securely hold the injected material while allowing drying of the water-based clay body and its shrinkage. The balance between grain composition, added water, and the compressibility of the mixture during printing and drying played a pivotal role in the particle suspension design and assessment. Furthermore, the moisture absorption of the particle suspension and the structural integrity of the layer bond of the fired ceramics were also assessed. The examined additive manufacturing process not only enables the production of meso-scale doubly curved ceramic shells with average overhang of 56° but also introduces a new practice for designing specialized surfaces and constructions. Full article

The development of biopolymer-based films represents a promising direction in the packaging industry that responds to stringent needs for sustainability, reducing the ecological impact. Traditional fossil-derived polymers present major concerns because of their long decomposition time and their significant contribution to the pollution of the environment. On the contrary, biopolymers such as chitosan, PVA, and PLA offer viable alternatives. This study aimed to obtain an innovative pH indicator for smart packaging using a synthetic non-toxic anthocyanin analogue dye incorporated in bio-based films to indicate meat freshness and quality. The pH-responsive color-changing properties of the dye make it suitable for developing intelligent films to monitor food freshness. The obtained polymeric films were characterized by FT-IR and UV–VIS spectroscopy, and their thermal properties were assessed using thermogravimetric methods. Moisture content, swelling capacity, and water solubility of the polymeric films were also evaluated. The sensitivity of the biopolymer–flavylium composite films to pH variations was studied in the pH range of 2 to 12 and noticeable color variations were observed, allowing the monitoring of the meat’s quality damage through pH changes. The pH-responsive films were applied directly on the surface or in the proximity of pork and chicken meat samples, to evaluate their colorimetric response to fresh and spoilt meat. This study can be the starting point for creating more durable packaging solutions leading to a circular economy. Full article