Search Results (171)

As the world transitions towards a more sustainable future, it is imperative to develop innovative solutions that address the pressing issue of plastic pollution. Microplastics, in particular, have become a significant concern due to their widespread presence in the environment and potential to interact with toxic pollutants. Organic compounds, which include a variety of harmful chemicals, such as pesticides and other industrial chemicals, are often released into the environment and can readily bind to microplastics. In this context, understanding the adsorption of organic compounds on microplastics is crucial for designing effective strategies to mitigate their environmental impacts. This study investigates the adsorption dynamics of organochlorine pesticides (OCPs) on polystyrene microplastics, exploring the influence of pH and contact time, as well as utilizing kinetic models and isothermal equations to elucidate the adsorption mechanism. The results suggest that the pH level has a negligible impact on the adsorption capacity of PS for OCPs. In contrast, the contact time plays a significant role in the amount of OCPs adsorbed onto the PS surface. Interestingly, a relatively short time of up to 6 h was sufficient to reach equilibrium. The adsorption of OCPs on PS follows a uniform pattern consistent with the Freundlich isotherm model, indicating a multilayer adsorption process. The use of kinetic models to describe the adsorption process was also found to be useful in understanding its mechanism. Specifically, the pseudo-second-order kinetic model proved to be a suitable descriptor for the adsorption process of organochlorine pesticides on PS. This study highlights the importance of understanding the interactions between microplastics and organic pollutants, which is crucial for developing sustainable solutions to mitigate the environmental impacts of plastic pollution, ultimately contributing to a more environmentally conscious future. Full article

This study investigates hydrogels based on 2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt (AMPS) copolymers, incorporating N-hydroxyethyl acrylamide (HEA) and 3-sulfopropyl acrylate potassium salt (SPA). The addition of HEA and SPA is designed to fine-tune the hydrogels’ water absorption and mechanical properties, ultimately enhancing their characteristics and expanding their potential for biomedical applications. A copolymer of AMPS, 2-carboxyethyl acrylate (CEA) combined with methacrylic acid (MAA) as poly(AMPS-stat-CEA-stat-MAA, PACM), was preliminarily synthesized. CEA and MAA were modified with allyl glycidyl ether (AGE) through ring-opening, yielding macromers with pendant allyl groups (PACM-AGE). Copolymers poly(AMPS-stat-HEA-stat-CEA-stat-MAA) (PAHCM) and poly(AMPS-stat-SPA-stat-CEA-stat-MAA) (PASCM) were also synthesized and modified with AGE to produce PAHCM-AGE and PASCM-AGE macromers. These copolymers and macromers were characterized by ¹H NMR, FT-IR, and GPC, confirming successful synthesis and functionalization. The macromers were then photocrosslinked into hydrogels and evaluated for swelling, water content, and mechanical properties. The results revealed that the PASCM-AGE hydrogels exhibited superior swelling ratios and water retention, achieving equilibrium water content (~92%) within 30 min. While the mechanical properties of HEA and SPA containing hydrogels show significant differences compared to PACM-AGE hydrogel (tensile strength 2.5 MPa, elongation 47%), HEA containing PAHCM-AGE has a higher tensile strength (5.8 MPa) but lower elongation (19%). In contrast, SPA in the PASCM-AGE hydrogels led to both higher tensile strength (3.7 MPa) and greater elongation (92%), allowing for a broader range of hydrogel properties. An initial study on drug delivery behavior was conducted using PACM-AGE hydrogels loaded with photosensitizers, showing effective absorption, release, and antibacterial activity under light exposure. These AMPS-based macromers with HEA and SPA modifications demonstrate enhanced properties, making them promising for wound management and drug delivery applications. Full article

In this paper, a gradient dynamics-based control method is proposed to directly tackle the singularity problem in the backstepping control design of the TORA system. This method is founded upon the construction of an energy-like positive function, which includes an auxiliary variable in terms of the intermediate virtual control law. On this basis, a gradient dynamics is created to obtain a new virtual control command, which is capable of making the auxiliary variable gradually approach zero, thereby mitigating the issue of division by zero. The core innovation is the integration of the gradient dynamics into the recursive backstepping design to overcome the singularity problem and stabilize the system at the equilibrium quickly. In addition, it rigorously proves that all the signals in the closed-loop control system are uniformly ultimately bounded, and the tracking errors converge to a small neighborhood around zero through a Lyapunov-based stability analysis. Comparative simulations demonstrate that the proposed approach not only avoids the singularity issue, but also achieves a better transient performance over other methods. Full article

We consider three different systems in a heat flow: an ideal gas, a van der Waals gas, and a binary mixture of ideal gases. We divide each system internally into two subsystems by a movable wall. We show that the direction of the motion of the wall, after release, under constant boundary conditions, is determined by the same inequality as in equilibrium thermodynamics $\mathrm{d}U-đQ\le 0$. The only difference between the equilibrium and non-equilibrium laws is the dependence of the net heat change, $đQ$, on the state parameters of the system. We show that the same inequality is valid when introducing the gravitational field in the case of both the ideal gas and the van der Waals gas in the heat flow. It remains true when we consider a thick wall permeable to gas particles and derive Archimedes’ principle in the heat flow. Finally, we consider the Couette (shear) flow of the ideal gas. In this system, the direction of the motion of the internal wall follows from the inequality $\mathrm{d}E-đQ-đW_s\le 0$, where $\mathrm{d}E$ is the infinitesimal change in total energy (internal plus kinetic) and $đW_s$ is the infinitesimal work exchanged with the environment due to the shear force imposed on the flowing gas. Ultimately, we synthesize all these cases within a general framework of the second law of non-equilibrium thermodynamics. Full article

An innovative composite structural element, the dune sand concrete-filled circular steel tube (DS-CFCST) column combines the mechanical performance of concrete-filled steel tube (CFST) columns with the environmental and economic benefits of dune sand (DS) concrete. However, current experimental investigations into DS-CFCST columns’ axial compressive behavior are limited. This study conducts a numerical analysis to examine the effects of varying DS replacement ratios and the influence of confinement on DS-CFCST stub columns. Finite element (FE) analysis reveals that DS-CFCST stub columns exhibit reduced ultimate bearing capacity compared to CFST columns, primarily due to weakened confinement effects at higher DS replacement ratios. A parametric study investigated the impacts of various design parameters on the ultimate axial bearing capacity of DS-CFCST stub columns. A practical design formula, based on equilibrium principles and the FE model, was developed. This formula simplifies the prediction of the ultimate load-bearing capacity of DS-CFCST stub columns using the superposition method. Its accuracy was validated by comparing it with experimental data and FE results. Lastly, a reliability analysis was performed, showing the DS-CFCST columns’ reliability index sensitivity to variations in concrete strength, steel yield strength, steel content ratio, load effect ratio, load combination factor, and DS replacement ratio. Full article

Skin stem cells (SCs) play a pivotal role in supporting tissue homeostasis. Several types of SCs are responsible for maintaining and regenerating skin tissue. These include bulge SCs and others residing in the interfollicular epidermis, infundibulum, isthmus, sebaceous glands, and sweat glands. The emergence of skin SCs commences during embryogenesis, where multipotent SCs arise from various precursor populations. These early events set the foundation for the diverse pool of SCs that will reside in the adult skin, ready to respond to tissue repair and regeneration demands. A network of molecular cues regulates skin SC behavior, balancing quiescence, self-renewal, and differentiation. The disruption of this delicate equilibrium can lead to SC exhaustion, impaired wound healing, and pathological conditions such as skin cancer. The present review explores the intricate mechanisms governing the development, activation, and differentiation of skin SCs, shedding light on the molecular signaling pathways that drive their fate decisions and skin homeostasis. Unraveling the complexities of these molecular drivers not only enhances our fundamental knowledge of skin biology but also holds promise for developing novel strategies to modulate skin SC fate for regenerative medicine applications, ultimately benefiting patients with skin disorders and injuries. Full article

In the rapidly evolving landscape of e-commerce, companies are increasingly focusing on their channel strategies to gain sustainable development. However, asymmetric demand information poses challenges to these decisions. This paper explores the interplay between a retailer’s information sharing strategy and a manufacturer’s channel strategy in a retailer-led green supply chain, where the manufacturer may establish an online channel to sell its green products directly. The dominant retailer has private demand information about the market and decides whether to share private information with the manufacturer. By establishing a game model, we analyze the impacts of information sharing and the manufacturer’s channel strategy on the payoffs for all the supply chain members, considering sustainability aspects such as the environmental benefits of green products and the efficiency of supply chain operations. The results show that information sharing benefits both the retailer and the manufacturer, irrespective of the establishment of an online channel. When the retailer shares demand information, opening an online channel benefits the manufacturer but benefits the retailer under certain conditions. Furthermore, through a numerical approach, we examine the strategic preferences of the firms and derive the equilibrium strategy. Interestingly, the manufacturer consistently prefers the scenario involving both an online channel and information sharing. The retailer’s preference, however, depends on the direct selling cost; it favors information sharing with or without an online channel based on this cost. Ultimately, our findings suggest that the equilibrium strategy can either be sharing information with an online channel or not sharing information without an online channel, which is contingent upon the direct selling cost and the forecast signal precision. These insights provide actionable strategies for enhancing the sustainability of supply chain operations. Full article

The equilibrium system is essential for the high-precision movement of the ultra-precision vertical axis. However, the complex assembly process makes orifice-throttling frictionless cylinders difficult to manufacture and prone to air hammering. Surface-throttling frictionless pneumatic cylinders effectively avoid these problems. This paper establishes an improved finite element method (FEM) model of a novel surface-throttling frictionless pneumatic cylinder to investigate its static performance. Furthermore, the static equilibrium calculation of the dual-cylinder system is concerned. The radial bearing capacity and support force requirements for the surface-throttling aerostatic bearings are obtained. The outcomes provide theoretical guidance for optimizing cylinder parameters. It ensures that the ultimately optimized cylinder meets the requirements for radial bearing capacity and support force of the ultra-precision vertical axis while minimizing air consumption. Finally, the accuracy of the proposed method is verified through computational fluid dynamics (CFD) calculation and experiments. Full article

Using density functional theory combined with the first principles calculation method of non-equilibrium Green’s function (NEGF-DFT), we studied the thermoelectric (TE) characteristics of one-dimensional γ-graphdiyne nanoribbons (γ-GDYNRs). The study found that the thermal conductivity of γ-GDYNRs has obvious anisotropy. At the same temperature and geometrical size, the lattice thermal conductivity of zigzag-edged γ-graphdiyne nanoribbons (γ-ZGDYNRs) is much lower than that of armchair-edged γ-graphdiyne nanoribbons (γ-AGDYNRs). We disclose the underlying mechanism for this intrinsic orientation. That is, γ-AGDYNRs have more phonon dispersion over the entire frequency range. Furthermore, the orientation dependence increases when the width of the γ-GDYNRs decreases. These excellent TE properties allow armchair-edged γ-graphdiyne nanoribbons with a planar width of 1.639 nm (γ-Z(2)GDYNRs) to have a higher power factor and lower thermal conductivity, ultimately resulting in a significantly higher TE conversion rate than other γ-GDYNR structures. Full article

This study aimed to investigate the liquid–liquid equilibrium (LLE) behavior of sesame fatty acid ethyl ester (FAEE) and methyl ester (FAME) in combination with glycerol and the co-solvents ethanol and methanol. FAEE and FAME were produced through the transesterification of mechanically extracted and purified sesame oil, using potassium hydroxide (KOH) as a homogeneous base catalyst. The reactions were conducted in ethanol and methanol to produce FAEE and FAME, respectively. Post-reaction, the products were separated and purified, followed by an analysis of the LLE behavior at 313.15 K and 323.15 K under atmospheric pressure (101.3 kPa). The experimental process for the miscibility analysis utilized a jacketed glass cell adapted for this study. Miscibility limits or binodal curves were determined using the turbidity-point method. Tie lines were constructed by preparing mixtures of known concentrations within the two-phase region, which allowed the phases to separate after agitation. Samples from both phases were analyzed to determine their composition. This study revealed that higher temperatures promoted greater phase separation and enhanced the biodiesel purification process. The NRTL model effectively correlated the activity coefficients with the experimental data, showing good agreement, with a root-mean-square deviation of 3.5%. Additionally, the data quality was validated using Marcilla’s method, which yielded an R² value close to 1. Attraction factors and distribution coefficients were also calculated to evaluate the efficiency of the co-solvents as extraction agents. The findings indicated higher selectivity for methanol than for ethanol, with varying degrees of distribution among the co-solvents. These results offer significant insights into enhancing biodiesel production processes by considering the effects of co-solvents on the LLE properties of mixtures, ultimately contributing to more efficient and cost-effective biodiesel production. Full article

In this paper, based on Meyerhof’s theory of homogeneous foundation, the limit equilibrium analysis method and unified logarithmic spiral sliding surface assumption are used to derive the theoretical formula for the ultimate bearing capacity of a layered foundation when the foundation is completely rough. It should be noted that this formula is only applicable to strip foundations of upper soft clay and lower sandy soil. In addition, a comparative analysis is conducted between theoretical formulas and semiempirical formulas for layered foundations. On the basis of verifying the reliability of the theoretical formula results, numerical simulation is carried out to further explore and analyze the influence of the width to depth ratio of the foundation, the strength parameters of the double-layer soil, and the thickness of the upper soft soil on the bearing capacity of the foundation. Research has shown that the formula for the bearing capacity of a layered foundation derived in this paper has a certain degree of error compared to Meyerhof’s semiempirical formula, but it is in good agreement with numerical simulation results and Hansen’s weighted average method results. The ratio of the width to depth of the foundation, the ratio of the cohesive force of the double-layer soil, and the tangent ratio of the internal friction angle have a significant positive correlation with the ultimate bearing capacity of the foundation. The increase in thickness of the overlying cohesive soil has a negative impact on the ultimate bearing capacity of the foundation, and the thicker the soil, the smaller the foundation’s bearing capacity. Full article

Medical data sharing is pivotal in enhancing accessibility and collaboration among healthcare providers, researchers, and institutions, ultimately leading to enhanced patient outcomes and more efficient healthcare delivery. However, due to the sensitive nature of medical information, ensuring both privacy and confidentiality is paramount. Access control-based data sharing methods have been explored to address these issues, but data privacy concerns still remain. Therefore, this paper proposes a secure and privacy-preserving data sharing scheme that achieves an equilibrium between data confidentiality and privacy. By leveraging key aggregate encryption and private set intersection techniques, our scheme ensures secure data sharing while protecting against the exposure of sensitive information related to data. We conduct informal and formal security analyses, including Burrow–Abadi–Needham logic and Scyther, to demonstrate its resilience against potential adversarial attacks. We also implement the execution time for cryptographic operations using multiprecision integer and a rational arithmetic cryptographic library and perform comparative analysis with existing related schemes in terms of security, computational cost, and time complexity. Our findings demonstrate a high level of security and efficiency, demonstrating that the proposed scheme contributes to the field by providing a solution that protects data privacy while enabling secure and flexible sharing of medical data. Full article

The thermal properties, microstructure, and mechanical properties of Fe-18Mn-3Ti (wt%) were investigated, focusing on the effects of different heat-treatment processes. Results revealed that the 450 °C warm-rolling sample (450 WR) exhibited promising mechanical properties. Specifically, this sample displayed a yield strength of 988 MPa, an ultimate tensile strength of 1052 MPa, and total elongation of 15.49%. Consequently, a favorable strength-ductility balance was achieved. The strain-hardening ability surpassed that of the cold rolling sample (CR). Microstructure analysis indicated the simultaneous occurrence of dynamic equilibrium between grain deformation and re-crystallization because of the co-influence of thermal and strain in the warm rolling process. This desirable mechanical property was attributed to the presence of a multi-phase (α-martensite, austenite, and ε-martensite) and heterogeneous microstructure. The improvement of ultimate tensile strength was based on grain refinement, grain co-deformation, and the transformation-induced plasticity (TRIP) effect in the early stage of plastic deformation (stage Ⅰ). The improvement of ultimate elongation (TEL) was ascribed to the TRIP effect in the middle stage of plastic deformation (stage Ⅱ). Full article

Previous studies have shown that feeding mice with food containing mantle tissue from Japanese scallops results in aggravated liver and kidney damage, ultimately resulting in mortality within weeks. The aim of this study is to evaluate the toxicity of scallop mantle in China’s coastal areas and explore the impact of scallop mantle toxins (SMT) on intestinal barrier integrity and gut microbiota in mice. The Illumina MiSeq sequencing of V3-V4 hypervariable regions of 16S ribosomal RNA was employed to study the alterations in gut microbiota in the feces of SMT mice. The results showed that intestinal flora abundance and diversity in the SMT group were decreased. Compared with the control group, significant increases were observed in serum indexes related to liver, intestine, inflammation, and kidney functions among SMT-exposed mice. Accompanied by varying degrees of tissue damage observed within these organs, the beneficial bacteria of Muribaculaceae and Marinifilaceae significantly reduced, while the harmful bacteria of Enterobacteriaceae and Helicobacter were significantly increased. Taken together, this article elucidates the inflammation and glucose metabolism disorder caused by scallop mantle toxin in mice from the angle of gut microbiota and metabolism. SMT can destroy the equilibrium of intestinal flora and damage the intestinal mucosal barrier, which leads to glucose metabolism disorder and intestinal dysfunction and may ultimately bring about systemic toxicity. Full article

Having a comprehensive knowledge of phase equilibrium is advantageous for industrial simulation and design of chemical processes. For further acquisition of primary data to facilitate the separation and purification of waste oil biodiesel systems, a liquid–liquid equilibrium (LLE) tank is deployed for the ternary system of waste oil biodiesel + methanol + glycerin, thereby enhancing the precision and efficiency of the process. The phase equilibrium system was constructed under the influence of atmospheric pressure at precise temperatures of 303.15 K, 313.15 K, and 323.15 K. The equilibrium components of each substance were analyzed by employing high-temperature gas chromatography, a sophisticated analytical method that enables the identification and quantification of individual components of a sample. Moreover, the ternary liquid–liquid equilibrium data were correlated by implementing the NRTL and UNIQUAC activity coefficient models. Subsequently, the binary interaction parameters of the ternary system were derived by conducting regression analysis. The experimental data demonstrated that the presence of lower methanol content in the system resulted in nearly immiscible biodiesel and glycerol phases, which ultimately facilitated the separation of biodiesel and glycerol. Conversely, with the increase in methanol content, the mutual solubility of biodiesel and glycerol was observed to increase gradually. The results showed that the calculated values of the NRTL and UNIQUAC models aligned well with the experimental values. The root-mean-square deviations of the NRTL and UNIQUAC models at 313.15 K were 2.76% and 3.56%, respectively. Full article